Q.1. The ratio of (E2 – E1) to (E4 – E3) for the hydrogen atom is approximately equal to
Ans. 15
Q.2. Assuming Rydberg’s constant (RH) to be 109670 cm–1, the longest wavelength line in the Lyman series of the hydrogen spectrum is
Ans. 1215.8 Å
λ = 1215.8 × 10–8 cm i.e.,
λ = 1215.8 Å
Q.3. The first excitation energy for hydrogen atom would be
Ans. 10.2 eV
Q.4. If electrons are excited to 4th shell in He+ ion, the number of wavelengths emitted by electrons during de-excitation are
Ans. 6
By nc2formula ie. Total number of transitions = n(n - 1)/2
Q.5. In Mn2+ ion, the number of unpaired electrons is
Ans. 5
Q.6. The radius of the first Bohr orbit of hydrogen atom (n = 1) is approximately 0.530 Å. The radius of the first excited state (n = 2) of hydrogen atom is
Ans. 2.12 Å
rn = r1 × n2 [for hydrogen atom]
rn = 0.53 × n2 Å [n = 2]
= 0.53 × 4
rn =2.12 Å.
Q.7. An element with atomic number 20 will be placed in the period of the periodic table
Ans. 4
Atomic number 20 → 1s22s22p63s23p64s2
Q.8. How many maximum quantum number can be same for two electrons in an atom.
Ans. 3
Maximum three quantum number can be same but fourth must be different.
Q.9. Find out the number of waves made by a Bohr electron in one complete revolution in its 3rd orbit.
Ans. 3
No of waves = principal quantum no.
n = 3
Q.10. How many unpaired electrons will be in 4f orbital of Gadolinium (64)?
Ans. 8
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