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Test: Properties of Amines (February 28) - NEET MCQ


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10 Questions MCQ Test - Test: Properties of Amines (February 28)

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Test: Properties of Amines (February 28) - Question 1

 Which one of the following is the weakest base in gaseous phase?

Detailed Solution for Test: Properties of Amines (February 28) - Question 1

 

As the number of alkyl group increases, due to +I effect the basicity of amines increases.

Test: Properties of Amines (February 28) - Question 2

Which one of the following is a tertiary amine?

Detailed Solution for Test: Properties of Amines (February 28) - Question 2

The correct answer is Option B.


Aniline : 

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Test: Properties of Amines (February 28) - Question 3

 Amines are basic in nature as they have:

Detailed Solution for Test: Properties of Amines (February 28) - Question 3

The correct answer is Option B.
Amines are basic in nature because the nitrogen atom in amines possesses a lone pair that can be donated.

According to the Lewis acid-base concept, amines can donate an electron pair, so they are Lewis bases.

Also, Brønsted-Lowry bases can accept a proton to form substituted ammonium ions.
So, amines are bases according to both the Lewis and the Brønsted-Lowry theories.

Test: Properties of Amines (February 28) - Question 4

Which of the following amine liberates nitrogen gas on reaction with HNO2 ?

Detailed Solution for Test: Properties of Amines (February 28) - Question 4

The correct answer is Option D.
Only primary amines liberate nitrogen gas on reaction with HNO2.

Test: Properties of Amines (February 28) - Question 5

Methylamine reacts with HNO2 to form _________.

Detailed Solution for Test: Properties of Amines (February 28) - Question 5

Test: Properties of Amines (February 28) - Question 6

The reaction of primary amine with Chloroform and ethanoic solution of KOH is called:

Detailed Solution for Test: Properties of Amines (February 28) - Question 6

The carbylamine reaction, also known as Hoffman's isocyanide test is a chemical test for detection of primary amines. In this reaction, the analyte is heated with alcoholic potassium hydroxide and chloroform. If a primary amine is present, the isocyanide (carbylamine) is formed which are foul smelling substances.

Test: Properties of Amines (February 28) - Question 7

Which of the following reaction is not given by aniline?

Detailed Solution for Test: Properties of Amines (February 28) - Question 7

Test: Properties of Amines (February 28) - Question 8

Aniline on treatment with sodium hypochlorite gives:

Detailed Solution for Test: Properties of Amines (February 28) - Question 8

The correct answer is Option C.

Test: Properties of Amines (February 28) - Question 9

 Which of the following has highest boiling point?

Detailed Solution for Test: Properties of Amines (February 28) - Question 9

The correct answer is Option D.

Because C4H9NH2 is primary amine and can form hydrogen bonding more than secondary amine (C2H5)2NH and tertiary amine C2H5N(CH3)2 . More hydrogen bonding  leads to strong bonding between the molecules, hence increases the boiling point.

Test: Properties of Amines (February 28) - Question 10

Hoffmann Bromamide Degradation reaction is shown by __________.

Detailed Solution for Test: Properties of Amines (February 28) - Question 10

The Correct answer is option B
Hoffman bromamide degradation reaction is shown by ArCONH2​.
Where the aryl amide is converted to aryl amine in the presence of Br2​ and NaOH

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