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All questions of The s - Block Elements for NEET Exam

The sequence of ioinic mobility in aqueous solution is : [2008]
  • a)
    K+ > Na+ > Rb+ > Cs+
  • b)
    Cs+ > Rb+ > K+ > Na+
  • c)
    Rb+ > K+ > Cs> Na+
  • d)
    Na+ > K+ > Rb+ > Cs+
Correct answer is option 'B'. Can you explain this answer?

Rohan Unni answered
Smaller the ion more is its ionic mobility in aqueous solution. Ionic radii of the given alkali metals is in the order Na+ < K+ < Rb+ < Cs+ and thus expected ionic mobility will be in the order Cs+ < Rb+ < K+ < Na+. However due to high degree of solvation (or hydration) because of lower size or high charge density, the hydrated ion size follows the order Cs+ < Rb+ < K+ < Na+ and thus conductivity order is Cs> Rb+ > K+ > Na+ i.e. option (b) is correct answer.

In which of the following the hydration energy is higher than the lattice energy? [2007]
  • a)
    MgSO4
  • b)
    RaSO4
  • c)
    SrSO4
  • d)
    BaSO4
Correct answer is option 'A'. Can you explain this answer?

The solubility of sulphates of alkaline earth metals decreases as we move down the group from Be to Ba due to the reason that ionic size increases down the group. The lattice energy remains constant because sulphate  ion is so large, so that small change in cationic sizes do not make any difference.
Thus the order:

In the replacement reaction
The reaction will be most favourable if M happens to be : [2012 M]
  • a)
    Na
  • b)
    K
  • c)
    Rb
  • d)
    Li
Correct answer is option 'C'. Can you explain this answer?

Tejas Chavan answered
Tertiary halide can show ionic reaction with MF so, MF should be most ionic for reaction to proceed forward. Hence ‘M’ should be ‘Rb’.

The correct order of the mobility of the alkali metal ions in aqueous solutions is [2006]
  • a)
    Na+ > K+ > Rb+ > Li+
  • b)
    K+ > Rb+ > Na+ > Li+
  • c)
    Rb+ >K+ > Na+ > Li+
  • d)
    Li+ > Na+ > K+ > Rb+
Correct answer is option 'C'. Can you explain this answer?

Ionic radii of alkali metals in water follows the order Li+ > Na+ > K+ > Rb+ > Cs+
Thus in aqueous solution due to larger ionic radius Li+ has lowest mobility and hence the correct order of ionic mobility is Li +  < Na  < K < Rb+

Which one of the following properties of alkali metals increases in magnitude as the atomic number rises ? [1989]
  • a)
    Ionic radius
  • b)
    Melting point
  • c)
    Electronegativity
  • d)
    First ionization energy.
Correct answer is option 'A'. Can you explain this answer?

Alkali metals are a group of elements in the periodic table that includes lithium, sodium, potassium, rubidium, cesium, and francium. These elements have similar properties, such as low electronegativity, high reactivity, and the tendency to lose one electron to form a univalent cation. Among the properties of alkali metals, the ionic radius increases in magnitude as the atomic number rises.

Explanation:

Ionic radius is the size of an ion, which is determined by the number of electrons and protons in the ion. In the case of alkali metals, the valence electron is located in the outermost shell, which means that the ionic radius depends on the size of the outermost shell. As the atomic number increases in the group, the number of electrons and protons also increases, which results in a larger size of the outermost shell. Therefore, the ionic radius increases in magnitude as the atomic number rises.

This trend can be observed in the periodic table by comparing the ionic radii of lithium, sodium, potassium, rubidium, cesium, and francium. The ionic radius increases from lithium to francium due to the increasing number of electrons and protons in the outermost shell.

In summary, the ionic radius of alkali metals increases in magnitude as the atomic number rises. This trend is due to the increasing size of the outermost shell as the number of electrons and protons increases.

Wh ich of the following atoms will have the smallest size ? [1989]
  • a)
    Mg
  • b)
    Na
  • c)
    Be
  • d)
    Li
Correct answer is option 'C'. Can you explain this answer?

Ayush Chavan answered
Within a period, the atomic size decreases from left to right.Further atomic size increases down the group. Hence the correct order is   i,e. Na > Mg > Li > Be.

Which of the following has largest size ? [1993]
  • a)
    Na
  • b)
    Na+
  • c)
    Na
  • d)
    Can’t be predicted
Correct answer is option 'C'. Can you explain this answer?

Kunal Rane answered
 A cation is always much smaller than the corresponding atom, whereas an anion is always larger than the corresponding atom, hence the size decreases in the order
Na- > Na > Na+

Which of the following compounds has the lowest melting point ? [2011]
  • a)
    CaCl2
  • b)
    CaBr2
  • c)
    CaI2
  • d)
    CaF2
Correct answer is option 'C'. Can you explain this answer?

Kunal Rane answered
Melting points of halides decreases as the size of the halogen increases. The correct order is CaF2 > CaCl2 > CaBr2 > CaI2

 The ease of adsorption of the hydrated alkali metal ions on an ion-exchange resins follows the order :[2012]
  • a)
    Li+ < K+ < Na+ < Rb+
  • b)
    Rb< K+ <Na+ < Li+
  • c)
    K+ < Na+ < Rb+ < Li+
  • d)
    Na+ < Li+ < K+ < Rb+
Correct answer is option 'B'. Can you explain this answer?

Dipanjan Mehta answered
All a lkali  metal salts are ionic (except Lithium) and soluble  in water due to the fact that cations get hydrated by water molecules. The  degree of hydration depends upon the size of the cation. Smaller the size of a cation, greater is its hydration energy.
Relative ionic radii :
Relative ionic radii in water or relative degree of hydration:

The correct order of increasing thermal stability of K2CO3, MgCO3, CaCO3 and BeCO3 is[2007]
  • a)
    BeCO3<  MgCO3 < CaCO3 < K2CO3
  • b)
    MgCO3 < BeCO3 < CaCO3 < K2CO3
  • c)
    K2CO3 < MgCO3 < CaCO3 < BeCO3
  • d)
    BeCO3 < MgCO3 < K2CO3 < CaCO3
Correct answer is option 'A'. Can you explain this answer?

Ashwini Khanna answered
As the basicity of metal hydroxides increases down the group from Be to Ba, the thermal stability of their carbonates also increases in the same order. Further group 1 compounds are more thermally stable than group 2 because their hydroxide are much basic than group 2 hydroxides therefore, the order of thermal stability is BeCO3 < MgCO3< CaCO3< K2CO3.

Which of the following oxides is not expected to react with sodium hydroxide? [2009]
  • a)
    CaO
  • b)
    SiO2
  • c)
    BeO
  • d)
    B2O3
Correct answer is option 'A'. Can you explain this answer?

Maya Sengupta answered
NaOH is a strong alkali. It combines with acidic and amphoteric oxides to form salts.
Since CaO is a basic oxide hence does not reacts with NaOH.

The alkali metals form salt-like hydrides by the direct synthesis at elevated temperature. The thermal stability of these hydrides decreases in which of the following orders ? [2008]
  • a)
    CsH  > RbH > KH > NaH > LiH
  • b)
    KH > NaH > LiH > CsH > RbH
  • c)
    NaH > LiH > KH > RbH > CsH
  • d)
    LiH > NaH > KH > RbH > CsH
Correct answer is option 'D'. Can you explain this answer?

The stability of alkali metal hydrides decreases from Li to Cs. It is due to the  fact that M–H bonds becomes weaker with increase in size of alkali metals as we move down the group from Li to Cs. Thus the order of stability of hydrides is LiH > NaH > KH > RbH > CsH i.e. option (d) is correct answer.

Which one of the alkali metals, forms only, the normal oxide, M2O on heating in air ? [2012]
  • a)
    Rb
  • b)
    K
  • c)
    Li
  • d)
    Na
Correct answer is option 'C'. Can you explain this answer?

Raghav Khanna answered
All the alkali metals when heated with oxygen form different types of oxides for example lithium forms lithium oxide (Li2O), sodium forms sodium peroxide (Na2O2), while K, Rb and Cs form their respective superoxides.

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