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All questions of Application of Schrodinger Wave Equation for Physics Exam

For a quantum wave particle, E = _____________ 
  • a)
    ℏ ω 
  • b)
    ℏ k 
  • c)
    ℏ ω/2 
  • d)
    ℏ k/2
Correct answer is option 'A'. Can you explain this answer?

Vedika Singh answered
The Energy of a wave particle is given as ℏ ω while the momentum of the particle is given as ℏ k. These are the desired relation.

For a particle of mass m, being acted upon by a force with potential energy function   a one-dimensional simple harmonic oscillator. If there is a wall at x = 0 so that  V = ∞ for x < 0, then the energy levels are equal to :
  • a)
  • b)
  • c)
  • d)
Correct answer is option 'D'. Can you explain this answer?

Pie Academy answered
The probability distributions for the quantum states of the oscillator without the barrier.

Infinite barrier at the origin means a node at origin, or the wave function goes to zero at x = 0.

By symmetry, the ground state will disappear, as well all the even states.  Odd values remain

Consider the solutions to particle in one dimensional box of length, L.
Which of the following is true for the group of functions  ψ2(x)
  • a)
    They form a complete set 
  • b)
    They are mutually orthogonal 
  • c)
    As we go up in energy, each successive state has one more node. i.e. ψ1(x) has none, ψ2(x) has one, ψ3(x)  has 2 and so on 
  • d)
    They are alternately even and odd with respect to the centre of the well
Correct answer is option 'A,B,C,D'. Can you explain this answer?

Pie Academy answered
The solution of a symmetric infinite potential well consists of 

Now, any function can be written as a linear combination of these functions (sin and cos)
 They form a complete let
The correct answers are: They are alternately even and odd with respect to the centre of the well, As we go up in energy, each successive state has one more node. i.e.  ψ1(x) has none, ψ2(x) has one, ψ3(x) has 2 and so on, They are mutually orthogonal, They form a complete set

The Steady-state form of Schrodinger wave equation is _____________ 
  • a)
    Linear 
  • b)
    Quadratic 
  • c)
    Differential equation
  • d)
    Derivable
Correct answer is option 'A'. Can you explain this answer?

Vedika Singh answered
The Steady-state Schrodinger Wave equation is a linear in the wave function Ψ. It means, that no term has \Psi with a degree greater than 1.

 Which of the following can be the solution of Schrondinger's equation?
  • a)
  • b)
  • c)
  • d)
Correct answer is option 'C'. Can you explain this answer?

Pie Academy answered
Concept:
  • Schrodinger wave equation is a mathematical expression that describes the energy and position of the electron in space and time, taking into account the matter wave nature of the electron inside an atom.
  • It is based on three considerations. They are:
    1. Classical plane wave equation, (wave which satisfies 
    2. Broglie’s Hypothesis of matter-wave, (the wavelength of matter-wave is inversely proportional to the linear momentum.)
    3. Conservation of Energy. (total energy = kinetic + potential)


Schrodinger equation gives us a detailed account of the form of the wave functions or probability waves that control the motion of some smaller particles.
The equation also describes how these waves are influenced by external factors.
Moreover, the equation makes use of the energy conservation concept that offers details about the behavior of an electron that is attached to the nucleus.
Explanation:
  1. For a wave to be a solution of Schrodinger's equation it must satisfy the following conditions:
    1. The wave function must be a single value.
    2. The wave function must be continuous.
    3. The wave function must be finite.
    4. The wave function must be differentiable at every point in space.
      Hence the correct option is 3.

A particle is in the second excited state (n=3) of a one-dimensional infinite potential well of width a. Which of the following is correct for the expectation values of x, x2, and p2?
  • a)
  • b)
  • c)
  • d)
Correct answer is option 'A'. Can you explain this answer?

Pie Academy answered
Wavefunction for n=3n = 3n=3:
The wavefunction is
:
Expectation value of xxx:
For all stationary states in an infinite potential well, the wavefunction is symmetric or antisymmetric around x = a / 2.
Hence, ⟨x⟩ = a / 2.
Expectation value of x2:
  • This integral evaluates to a/ 4 for n = 3.
  • Expectation value of p2:
    From the energy eigenvalue relation:

A particle is in the ground state of a one-dimensional infinite potential well with boundaries at x=0 and x=a. Which of the following statements is correct?
  • a)
    The probability density is maximum at the center of the well (x = a / 2).
  • b)
    The expectation value of position, ⟨x⟩, is zero.
  • c)
    The energy eigenvalue of the ground state is inversely proportional to a2.
  • d)
    The expectation value of kinetic energy is zero.
Correct answer is option 'A'. Can you explain this answer?

Pie Academy answered
Wavefunction for the Ground State:
  • The ground state wavefunction for an infinite potential well is:
  • The corresponding probability density is:
This is maximum at x = a/2 because sin2 reaches its peak value (1) at the center of the well.
Expectation Value of Position (⟨x⟩):
  • The wavefunction is symmetric about x = a/2, so the expectation value of position is:
  • Hence, it is not zero.
  • Energy Eigenvalue of the Ground State:
    The energy eigenvalue for the ground state (n=1) is
  • The energy is inversely proportional to a2, as larger aaa allows the particle to occupy lower-energy states.
  • Expectation Value of Kinetic Energy:
    The expectation value of kinetic energy is nonzero because the particle is confined, and its wavefunction has a curvature (derivative). For the ground state:

Which of the following can be a wave function? 
  • a)
    tan x 
  • b)
    cot x 
  • c)
    sec x
  • d)
    sin x 
Correct answer is option 'D'. Can you explain this answer?

Pie Academy answered
A wave function must satisfy the following key properties:
  1. Single-valued: The wave function must have a unique value for every point in space.
  2. Continuous and finite: It must not have any discontinuities or infinite values.
  3. Normalizable: The integral of the squared wave function over all space must converge to a finite value.
Now, analyzing the options:
  • Option A: tanx
    The tangent function has discontinuities at x = π/2, 3π/2,…, making it invalid as a wave function.
  • Option B: cotx
    The cotangent function has discontinuities at x = 0, π, 2π,…, so it cannot represent a wave function.
  • Option C: secx
    The secant function has discontinuities at x = π/2, 3π/2,…, disqualifying it as a wave function.
  • Option D: sinx
    The sine function is continuous, finite, and single-valued across all points. It satisfies the criteria for a valid wave function.

For the above cases of one-dimensional infinite and finite potential wells which of the following is true?
  • a)
    Energy levels are the same in both cases 
  • b)
    Energy levels are same,  in both cases. 
  • c)
    Energy levels are different 
  • d)
    None of the above. 
Correct answer is option 'B'. Can you explain this answer?

Pie Academy answered
  1. Energy Levels for an Infinite Potential Well: In a one-dimensional infinite potential well, the energy levels are quantized and given by:
    where:
    • n is the quantum number (n = 1, 2, 3,…),
    • h is Planck's constant,
    • m is the particle's mass,
    • L is the width of the well.
  2. Energy Levels for a Finite Potential Well: In a finite potential well, the energy levels are also quantized but slightly lower than those in the infinite potential well due to the finite height of the potential, which allows tunneling effects. However, the functional form remains approximately the same for lower energy levels:
    for sufficiently deep wells.
  3. Harmonic Oscillator Energy Levels: The energy levels given in Option A:
    represent the quantized energy levels for a quantum harmonic oscillator, not a potential well. Hence, Option A is incorrect.
Analysis of Options:
  • Option A: Incorrect, as this describes the energy levels of a quantum harmonic oscillator, not a one-dimensional potential well.
  • Option B: Correct, because the energy levels for both the infinite and finite potential wells are approximately given by ​, especially for deep finite wells.
  • Option C: Incorrect, as the energy levels are approximately the same in form for both cases, differing only due to tunneling effects in the finite case.
  • Option D: Incorrect, as Option B is correct.

If a particle is confined to a one dimensional box of length a  with the centre of the box at x = 0. Then, choose the correct option.
  • a)
    The energy levels are 
  • b)
    Both the normalization constant and the energy levels are different from the case of the box centered at x = a/2
  • c)
    The normalization constant will be same as in the case of a box centered at x = a/2
  • d)
    The solutions of this case can be obtained by substituting x  by  in 
Correct answer is option 'A,C,D'. Can you explain this answer?

Vedika Singh answered
The case of a symmetric one dimensional box, is similar to the box from x = 0 to a. The wave functions can be derived from the later case by putting  in place of x.
The correct answers are: The solutions of this case can be obtained by substituting x  by in  The normalization constant will be same as in the case of a box centered x = a/2 , The energy levels are 

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