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All questions of Thermal Expansion, Gas Laws & Kinetic Theory of Gases for JAMB Exam

When water is heated from 0° C to 20° C its volume:
  • a)
    first decreases and then increases
  • b)
    goes on increasing
  • c)
    remains constant up to 15°C and then increases
  • d)
    goes on decreasing
Correct answer is option 'A'. Can you explain this answer?

Pooja Shah answered
When water is heated from 0°C, its volume decreases because its density increases and you can see this effect upto 4°C. Since the density of ice is maximum at 4°C, afterwards as the density decreases the volume increases. The main reason for this is hydrogen bond in ice gets cleaved due to the melting of ice.

Oxygen and nitrogen in two enclosures have the same mass, volume and pressure. The ratio of the temperature of oxygen to that of nitrogen is:
  • a)
    8/7
  • b)
    49/64
  • c)
    1
  • d)
    7/8
Correct answer is option 'A'. Can you explain this answer?

Neha Joshi answered
For same mass the ratio of moles of oxygen to that of nitrogen is 14:16 = 7:8
And we know that PV = nRT
Hence as V and P are also same, ratio of temperature of oxygen to that of nitrogen is inverse of the ratio of moles that is 8:7

Water contract on heating between the temperatures
  • a)
    0°C to 4°C
  • b)
    0°K to 4°K
  • c)
    0o K to 273 K
  • d)
    0°F to 4°F
Correct answer is option 'A'. Can you explain this answer?

Geetika Shah answered
When water is heated from 0oC, its volume decreases because its density increases and you can see this effect upto 4oC. Since the density of ice is maximum at 4oC, afterwards as the density decreases the volume increases. The main reason for this is hydrogen bond in ice gets cleaved due to the melting of ice.

Three moles of an ideal monoatomic gas is initially in the state A shown in the adjoining pressure-temperature graph. It is taken to state B without changing its pressure. If R is the universal gas constant, the work done by the gas in this process is 
81531_kra17
  • a)
    600 R
  • b)
    400 R
  • c)
    300 R
  • d)
    200 R
Correct answer is option 'A'. Can you explain this answer?

The work done by the gas in taking it from state A to state B = PΔV where ΔW is the increase in volume at constant pressure P. 
We have PV = μRT where p is the number of moles in the sample of the gas and R is the universal gas constant. 
Therefore we have PΔV = μR ΔT = 3 xR(450 - 250) = 600R 

Which one of the following quantities can be zero on an average for the molecules of an ideal gas in equilibrium?
  • a)
    Speed
  • b)
    Momentum
  • c)
    Kinetic Energy
  • d)
    Density
Correct answer is 'B'. Can you explain this answer?

Riya Banerjee answered
In case of ideal gases the average velocity is always zero. Hence the average momentum is zero. 
Whereas average speed is non- zero so the kinetic energy is also non-zero,  as these two are scalar quantities.

The temperature for which the reading on Celsius and Fahrenheit scales are identical is
  • a)
    -273°C, -273 °F
  • b)
    -30°C, -30 °F
  • c)
    0 °C, 0 °F
  • d)
    -40 °C, -40 °F
Correct answer is option 'D'. Can you explain this answer?

Preeti Iyer answered
The Celsius and Fahrenheit are two important temperature scales. The Fahrenheit scale is used primarily in the United States, while Celsius is used throughout the world. The two scales have different zero points and the Celsius degree is bigger than the Fahrenheit one. There is one point on the Fahrenheit and Celsius scales where the temperatures in degrees are equal. This is -40 degree C and -40 degree F.

Can you explain the answer of this question below:

Two identical rectangular strips, one of copper and the other of steel, are riveted as shown to form a bi-metal strip. On heating, the bi-metal strip will

72601_ra1 (1)

  • A:

    bend with steel on the concave side

  • B:

    get twisted

  • C:

    remain straight

  • D:

    bend with steel on the convex side

The answer is a.

Nandini Patel answered
On heating, the copper strip will suffer greater elongation and hence the bimetal strip will bend with the steel strip on the concave side. 
[Bimetal strips are widely used in thermal switching applications such as automatic electric iron].

The number of degrees of freedom a diatomic molecule is
  • a)
    6
  • b)
    5.0
  • c)
    3
  • d)
    5.3
Correct answer is option 'D'. Can you explain this answer?

Akshara Chopra answered
Explanation:Degrees of freedom of a system refers to the possible independent motions a system can have.the total degrees of freedom describing the motion of a diatomic molecule is 5.3 for translation and 2 for rotation

Mean free path is the
  • a)
    maximum distance between collisions
  • b)
    minimum distance between collisions
  • c)
    average distance between collisions
  • d)
    (maximum distance + minimum distance )/ 2 between collisions
Correct answer is option 'C'. Can you explain this answer?

Explanation:the mean free path is the average distance traveled by a moving particle (such as an atom, a molecule, a photon) between successive impacts (collisions), which modify its direction or energy or other particle properties.

At absolute zero temperature may be defined as that temperature at which
  • a)
    Volume is maximum
  • b)
    Root mean square velocity of the gas molecule reduces to zero
  • c)
    Temperature is 273 K
  • d)
    Mass of molecules of gas is zero
Correct answer is option 'B'. Can you explain this answer?

Gaurav Kumar answered
At 0K temperature we know that there is no molecular motion, that is the KE of the particles gets 0. Thus we can say the combined KE of a gaseous system is zero, but as there combined mass cant be zero thus the combined of the square of velocities of the particles is zero, which means that the root mean square velocity of the gas is zero.

When the temperature goes up, the pressure inside a rigid container will _____.
  • a)
    remain unchanged
  • b)
    go down
  • c)
    cause particles to cool
  • d)
    go up
Correct answer is option 'D'. Can you explain this answer?

Vijay Bansal answered
The pressure law states that for a constant volume of gas in a sealed container the temperature of the gas is directly proportional to its pressure. This can be easily understood by visualising the particles of gas in the container moving with a greater energy when the temperature is increased.

One mole of hydrogen gas is heated at constant pressure from 300 K to 420 K. Calculate the energy transferred by heat to the gas
  • a)
    3.86 kJ
  • b)
    3.49 kJ
  • c)
    3.66 kJ
  • d)
    3.26 kJ
Correct answer is option 'B'. Can you explain this answer?

To calculate the energy transferred by heat to the gas, we can use the formula:

q = nCΔT

Where:
q = energy transferred by heat
n = number of moles of gas
C = molar heat capacity at constant pressure
ΔT = change in temperature

Given:
n = 1 mole
ΔT = 420 K - 300 K = 120 K

We need to find the value of C, the molar heat capacity at constant pressure.

The molar heat capacity at constant pressure (Cp) for an ideal gas can be calculated using the equation:

Cp = 5/2R

Where:
R = ideal gas constant = 8.314 J/mol·K

Substituting the values, we have:

Cp = 5/2 * 8.314 J/mol·K = 20.785 J/mol·K

Now, we can substitute the values of n, C, and ΔT into the formula:

q = (1 mole)(20.785 J/mol·K)(120 K)
q = 2494.2 J

To convert the energy from joules to kilojoules, we divide by 1000:

q = 2494.2 J / 1000 = 2.4942 kJ

Therefore, the energy transferred by heat to the gas is approximately 2.4942 kJ. None of the given options matches this value, so we need to consider significant figures.

The given temperature values are given to three significant figures (300 K and 420 K). Therefore, our final answer should also be rounded to three significant figures.

Rounding 2.4942 kJ to three significant figures, we get:

2.49 kJ

Among the given options, option B, 3.49 kJ, is the closest match to our rounded answer.

The relation between coefficient of volume expansion  and coefficient of linear expansion  is
  • a)
    αv = 2α1
  • b)
    α1 = 3αv
  • c)
    αv = 3α1
  • d)
    α1 = 2αv
Correct answer is option 'C'. Can you explain this answer?

This is simple,because the coefficients of linear expansion A,areal expansion B,and volume expansion G,are in the ratio of 1:2:3 i.e; A:B:G::1:2:3 Hence,G=3A

In which case are the atoms relatively rigidly fixed?
  • a)
    gases
  • b)
    liquids and gases
  • c)
    solids
  • d)
    liquids
Correct answer is option 'C'. Can you explain this answer?

Pranav Saha answered
Explanation:
Atoms in a gas are well separated with no regular arrangement. Atoms vibrate and move freely at high speeds
Atoms in a liquid are close together with no regular arrangement. Atoms vibrate, move about, and slide past each other.
Atoms in a solid are tightly packed, usually in a regular pattern. Atoms vibrate (jiggle) but generally do not move from place to place.

According to Atomic Hypothesis: little particles of atom
  • a)
    attract each other when they are at small distance apart, but repel upon being squeezed into one another
  • b)
    repel each other when they are at small distance apart, but attract upon being squeezed into one another
  • c)
    repel each other when they are at small distance apart, but repel upon being squeezed into one another
  • d)
    repel each other when they are at large distance apart, but attract upon being separated from one another
Correct answer is option 'A'. Can you explain this answer?

Saikat Sharma answered
Explanation:At room temperature (=300K) the noble gases are all in the gas phase, they are banging around and colliding into one another like little pool balls. At this temperature, when the atoms collide they appear to elastically bounce off of one another, but this bounce is actually a result of atomic repulsion. The atoms are traveling so fast and they approach each other so quickly that their momentum 'squeezes' them together until the atomic repulsion pushes them back apart.

Four cylindrical rods of different radii and lengths are used to connect two heat reservoirs at fixed temperatures t1 and t2 respectively. From the following pick out the rod which will conduct the maximum quantity of heat:
  • a)
    Radius 1 cm, length 2 m
  • b)
    Radius 1 cm, length 1 m
  • c)
    Radius 2 cm, length 4 m
  • d)
    Radius 3 cm, length 8 m
Correct answer is option 'D'. Can you explain this answer?

Neha Sharma answered
The rate of heat transfer is directly proportional to the bisectional surface area of the solid and inversely proportional to its parallel length. 
That is heat conduction rate say H ∝ r2
∝ 1/L
I.e ∝ r2/L
Hence the conduction would be
maximum in case in which  r2/L ratio is largest.

The average kinetic energy of a molecule in an ideal gas is
  • a)
    proportional to the pressure
  • b)
    depends on the nature of the ideal gas
  • c)
    proportional to the absolute temperature of the gas
  • d)
    proportional to the volume
Correct answer is option 'C'. Can you explain this answer?

Priya Patel answered
SHOW THAT THE AVERAGE TRANSLATIONAL KINETIC ENERGY OF THE MOLECULES OF A GAS IS DIRECTLY PROPORTIONAL TO ABSOLUTE TEMPERATURE. kinetic energy of the molecules of a gas is directly proportional to absolute temperature.

The number of degrees of freedom a monatomic molecule is
  • a)
    2
  • b)
    1
  • c)
    3.0
  • d)
    4
Correct answer is option 'C'. Can you explain this answer?

Pooja Shah answered
Explanation:Degrees of freedom of a system refers to the possible independent motions a system can have.Monoatomic gas molecule can have 3 independent motion and hence have 3 degrees of freedom (all are translational).

Kinetic theory
  • a)
    correctly explains specific heat capacities of many gases
  • b)
    correctly explains specific heat capacities of super cooled liquids
  • c)
    correctly explains specific heat capacities of many solids
  • d)
    correctly explains specific heat capacities of many liquids
Correct answer is option 'A'. Can you explain this answer?

Ishan Ghosh answered


Explanation:

Kinetic Theory of Gases and Specific Heat Capacities:

The kinetic theory of gases is a model that describes the behavior of gases based on the motion of their particles. When it comes to specific heat capacities, the kinetic theory of gases correctly explains the specific heat capacities of many gases.

Specific Heat Capacities of Gases:

- According to the kinetic theory of gases, the specific heat capacity of a gas is related to the degrees of freedom of its molecules.
- The specific heat capacity of a gas depends on the translational, rotational, and vibrational motions of its molecules.
- The kinetic theory predicts that for monatomic gases, which have only translational motion, the specific heat capacity at constant volume is 3/2 R, where R is the gas constant.
- For diatomic gases, which can also rotate, the specific heat capacity at constant volume is 5/2 R.

Experimental Evidence:

- Experimental measurements of specific heat capacities of gases have been found to be in good agreement with the predictions of the kinetic theory.
- This provides strong evidence that the kinetic theory of gases correctly explains the specific heat capacities of many gases.

Therefore, option A is correct as the kinetic theory of gases correctly explains the specific heat capacities of many gases based on the motion of their particles.

The molecule of a monatomic gas has only three translational degrees of freedom. Thus, the average energy of a molecule at temperature 'T' is __________.
  • a)
    3kB​T
  • b)
    (1/3)kB​T
  • c)
    (3/2)kBT
  • d)
    (3/4)kBT
Correct answer is option 'C'. Can you explain this answer?

Understanding Degrees of Freedom
In thermodynamics, the degrees of freedom of a molecule refer to the number of independent ways in which it can move. For a monatomic gas, the gas molecules can move in three-dimensional space, resulting in three translational degrees of freedom.
Energy and Temperature Relationship
The average energy of a molecule in a gas is related to its temperature through the equipartition theorem. This theorem states that each degree of freedom contributes an average energy of (1/2)kBT, where kB is the Boltzmann constant and T is the absolute temperature.
Calculation of Average Energy
Since a monatomic gas has three translational degrees of freedom, we can calculate the average energy as follows:
- Each degree of freedom contributes (1/2)kBT.
- Therefore, for three degrees of freedom:
- Total average energy = 3 * (1/2)kBT = (3/2)kBT.
Conclusion
Thus, the average energy of a molecule in a monatomic gas at temperature T is:
- (3/2)kBT.
This is why option 'C' is correct. The average energy reflects the kinetic energy associated with the translational motion of the gas molecules. Understanding these principles is crucial for grasping the behavior of gases in thermodynamics.

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