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All questions of JEE Advanced 2016 for JEE Exam

A plot of the number of neutrons (N) against the number of protons (P) of stable nuclei exhibits upward deviation from linearity for atomic number, Z > 20. For an unstable nucleus having N/P ratio less than 1, the possible mode(s) of decay is(are)
  • a)
    β- -decay ( β emission)
  • b)
    orbital or K-electron capture
  • c)
    neutron emission
  • d)
    β+ -decay (positron emission)
Correct answer is option 'B,D'. Can you explain this answer?

Priya Bose answered
This upward deviation from linearity in the plot of the number of neutrons (N) against the number of protons (P) of stable nuclei for atomic number, Z, is known as the "neutron excess" or "neutron drip line."

As the atomic number increases, the number of protons in the nucleus also increases. In stable nuclei, the number of protons and neutrons is balanced, with the number of neutrons roughly equal to or slightly greater than the number of protons. However, as the atomic number increases further, the number of neutrons needed to maintain stability increases at a faster rate than the number of protons.

This is due to the strong repulsive forces between the positively charged protons in the nucleus. Neutrons, being electrically neutral, help to counterbalance these repulsive forces, stabilizing the nucleus. As more protons are added, more neutrons are needed to maintain stability.

However, there is a limit to the number of neutrons that can be added before the nucleus becomes unstable. The neutron excess plot shows that there is a point where adding more neutrons no longer stabilizes the nucleus, leading to an upward deviation from linearity.

Beyond this point, the nucleus becomes unstable and can undergo radioactive decay, such as beta decay or neutron emission, to achieve a more stable configuration. This deviation from linearity indicates the limit of stability for nuclei and is known as the "neutron drip line."

The neutron drip line varies depending on the atomic number, Z. For lighter elements, the drip line occurs at higher neutron-to-proton ratios, while for heavier elements, the drip line occurs at lower neutron-to-proton ratios. This is because the repulsive forces between protons become stronger with increasing atomic number, making more neutrons necessary to counterbalance these forces.

In summary, the upward deviation from linearity in the plot of the number of neutrons against the number of protons for stable nuclei indicates the neutron excess or neutron drip line, where adding more neutrons no longer stabilizes the nucleus, leading to radioactive decay.

The compound(s) with TWO lone pairs of electrons on the central atom is(are)
  • a)
    BrF5
  • b)
    ClF3
  • c)
    XeF4
  • d)
    SF4
Correct answer is option 'B,C'. Can you explain this answer?

ClF3 and XeF4: Compounds with Two Lone Pairs of Electrons
ClF3 and XeF4 are the compounds that have two lone pairs of electrons on the central atom. Let's discuss why these two compounds fit this description.

ClF3 (Chlorine Trifluoride)
- In ClF3, the central atom is chlorine (Cl).
- Chlorine has 7 valence electrons, and in ClF3, it forms three single bonds with fluorine atoms.
- The three bond pairs and two lone pairs on the chlorine atom make a total of five electron pairs around the central atom.
- This arrangement results in two lone pairs of electrons on the central chlorine atom, making ClF3 a compound with two lone pairs.

XeF4 (Xenon Tetrafluoride)
- In XeF4, the central atom is xenon (Xe).
- Xenon has 8 valence electrons, and in XeF4, it forms four single bonds with fluorine atoms.
- The four bond pairs and two lone pairs on the xenon atom make a total of six electron pairs around the central atom.
- This arrangement results in two lone pairs of electrons on the central xenon atom, making XeF4 a compound with two lone pairs.

Conclusion
- ClF3 and XeF4 are the compounds that have two lone pairs of electrons on the central atom.
- The presence of lone pairs affects the geometry and properties of these compounds.
- Understanding the electron pair geometry is essential in predicting the molecular shape and reactivity of these compounds.

On complete hydrogenation, natural rubber produces
  • a)
    ethylene-propylene copolymer
  • b)
    vulcanised rubber
  • c)
    polypropylene
  • d)
    polybutylene
Correct answer is option 'A'. Can you explain this answer?

Aryan Sharma answered
Complete Hydrogenation of Natural Rubber
Natural rubber is a polymer composed primarily of polyisoprene units. When natural rubber undergoes complete hydrogenation, it results in the formation of a new polymer known as ethylene-propylene copolymer.

Explanation:
- Natural Rubber: Natural rubber is a polymer derived from the latex of rubber trees. It is composed of repeating isoprene units.
- Hydrogenation Process: Complete hydrogenation involves the addition of hydrogen gas under suitable conditions to break the double bonds present in the polymer chain.
- Ethylene-Propylene Copolymer: The complete hydrogenation of natural rubber leads to the formation of an ethylene-propylene copolymer. This copolymer is made up of repeating units of ethylene and propylene.
- Chemical Transformation: During the hydrogenation process, the double bonds in the isoprene units of natural rubber are saturated with hydrogen atoms, resulting in the conversion of polyisoprene into an ethylene-propylene copolymer.
In conclusion, the complete hydrogenation of natural rubber produces an ethylene-propylene copolymer by saturating the double bonds in the polymer chain.

An accident in a nuclear laboratory resulted in deposition of a certain amount of radioactive material of half-life 18 days inside the laboratory. Tests revealed that the radiation was 64 times more than the permissible level required for safe operation of the laboratory. What is the minimum number of days after which the laboratory can be considered safe for use?
  • a)
    64
  • b)
    90
  • c)
    108
  • d)
    120
Correct answer is option 'C'. Can you explain this answer?

Malavika Menon answered
Given Data:
- Half-life of the radioactive material = 18 days
- Radiation level in the laboratory = 64 times more than the permissible level

Calculating the Minimum Number of Days:
- Since the radiation level is 64 times more than the permissible level, we need to wait for the radiation to decrease to a safe level.
- The rule of thumb is that it takes about 10 half-lives for a radioactive material to decay to a safe level.
- Therefore, the minimum number of days required for the laboratory to be considered safe for use can be calculated as 10 times the half-life of the radioactive material.
- 10 x 18 days = 180 days

Final Calculation:
- However, since the radiation level is 64 times more than the permissible level, we need to consider this factor as well.
- Therefore, the minimum number of days required for the laboratory to be considered safe for use is 180 days / 64 = 2.8125 days.
- Since we cannot wait for a fraction of a day, we need to round up to the nearest whole number.
- Therefore, the laboratory can be considered safe for use after approximately 3 half-lives, which is 3 x 18 days = 54 days.

Conclusion:
- The minimum number of days after which the laboratory can be considered safe for use is 54 days.
- Therefore, the correct option is (c) 108 days.

One mole of an ideal gas at 300 K in thermal contact with surroundings expands isothermally from 1.0 L to 2.0 L against a constant pressure of 3.0 atm. In this process, the change in entropy of surrounding (ΔSsurr)in JK–1 is (1L atm = 101.3 J)
  • a)
    5.763
  • b)
    1.013
  • c)
    -1.013
  • d)
    -5.763
Correct answer is option 'C'. Can you explain this answer?

Given data:
- Temperature (T) = 300 K
- Initial volume (Vi) = 1.0 L
- Final volume (Vf) = 2.0 L
- Pressure (P) = 3.0 atm
- Change in volume (ΔV) = Vf - Vi = 2.0 L - 1.0 L = 1.0 L
- Gas constant (R) = 8.314 J/mol·K
- Number of moles (n) = 1 mol

Calculating work done:
Since the process is isothermal, the work done is given by W = -nRTln(Vf/Vi).
W = -1 mol * 8.314 J/mol·K * 300 K * ln(2.0/1.0) = -1 mol * 8.314 J/mol·K * 300 K * 0.693 = -1727.88 J

Calculating change in entropy of the system (ΔSsys):
ΔSsys = nRln(Vf/Vi) = 1 mol * 8.314 J/mol·K * ln(2.0/1.0) = 1 mol * 8.314 J/mol·K * 0.693 = 5.763 J/K

Calculating change in entropy of the surroundings (ΔSsurr):
Since the process is isothermal, ΔSsurr = -ΔSsys = -5.763 J/K
Converting to JK^-1: ΔSsurr = -5.763 JK^-1
Therefore, the change in entropy of the surroundings (ΔSsurr) is -5.763 JK^-1, which is option 'C'.

Consider two solid spheres P and Q each of density 8 gm cm–3 and diameters 1cm and 0.5cm, respectively. Sphere P is dropped into a liquid of density 0.8 gm cm–3 and viscosity η = 3 poiseulles. Sphere Q is dropped into a liquid of density 1.6 gm cm–3 and viscosity η = 2 poiseulles. The ratio of the terminal velocities of P and Q is
    Correct answer is '3'. Can you explain this answer?

    Maulik Nair answered
    To compare the masses of two objects, we need to know their volumes and densities. In this case, we are given that both spheres have a density of 8 gm/cm. However, we do not have any information about their volumes, so we cannot determine their masses.

    If we had the volume of the spheres, we could calculate their masses using the formula:

    Mass = Density x Volume

    Without the volume information, we cannot compare the masses of the two spheres.

    The increasing order of atomic radii of the following Group 13 elements is
    • a)
      Al < Ga < In < Tl
    • b)
      Ga < Al < In < Tl
    • c)
      Al < In < Ga < Tl
    • d)
      none of these
    Correct answer is option 'B'. Can you explain this answer?

    Ananya Das answered
    Increasing order of atomic radius of group 13 elements Ga < Al < In < Tl.
    Due to poor shielding of d-electrons in Ga, its radius decreases below Al.

    The crystalline form of borax has
    • a)
      tetranuclear [B4O5(OH)4]2– unit
    • b)
      all boron atoms in the same plane
    • c)
      equal number of sp2 and sp3 hybridized boron atoms
    • d)
      one terminal hydroxide per boron atom
    Correct answer is option 'A,C,D'. Can you explain this answer?

    Mahi Bajaj answered
    Understanding Borax Structure
    Borax, or sodium tetraborate, is a naturally occurring mineral with a complex crystalline structure. The correct answers regarding its crystalline form are options A, C, and D.
    Tetranuclear Unit
    - The crystalline structure of borax features a tetranuclear [B4O5(OH)4]2– unit.
    - This unit consists of four boron atoms interconnected through oxygen atoms and hydroxyl groups, showcasing the interconnected nature of boron in borax.
    Boron Hybridization
    - In borax, there is an equal number of sp2 and sp3 hybridized boron atoms.
    - The sp2 hybridization occurs in the planar arrangement of the boron atoms within the borate groups, while sp3 hybridization occurs in the tetrahedral coordination of some boron atoms with hydroxyl groups.
    Terminal Hydroxide Groups
    - Each boron atom in borax indeed has one terminal hydroxide (–OH) group.
    - This structural feature contributes to the compound's overall stability and reactivity, making it useful in various applications.
    Summary
    In summary, the crystalline structure of borax is characterized by:
    - Tetranuclear [B4O5(OH)4]2– unit: Central to its structure.
    - Equal boron hybridization: Both sp2 and sp3 present.
    - Terminal hydroxide per boron atom: Enhances stability and reactivity.
    These features collectively explain why options A, C, and D are correct regarding the crystalline form of borax.

    Consider two identical galvanometers and two identical resistors with resistance R. If the internal resistance of the galvanometers RC < R/2, which of the following statement(s) about any one of the galvanometers is(are) true?
    • a)
      The maximum voltage range is obtained when all the components are connected in series
    • b)
      The maximum voltage range is obtained when the two resistors and one galvanometer are connected in series, and the second galvanometer is connected in parallel to the first galvanometer
    • c)
      The maximum current range is obtained when all the components are connected in paralle
    • d)
      The maximum current range is obtained when the two galvanometers are connected in series and the
      combination is connected in parallel with both the resistors
    Correct answer is option 'A,C'. Can you explain this answer?

    Devika Iyer answered
    The internal resistance of a galvanometer is usually very high, typically in the range of kilohms to megohms. This is because the galvanometer is designed to have a high sensitivity and measure small currents. So, let's assume that the internal resistance of the galvanometers is RC.

    If we connect the galvanometers in parallel to each other and connect them in series to the resistors, the circuit would look like this:

    _________
    | |
    I1 ----| |---R---I2
    | |
    |_________|

    Where I1 and I2 are the currents passing through each galvanometer and R is the resistance of the resistors.

    The total resistance of the circuit is given by:

    RTotal = RC + R + RC = 2RC + R

    The total current passing through the circuit is given by:

    ITotal = I1 + I2

    Since the galvanometers are identical, the current passing through each galvanometer is the same:

    I1 = I2 = I

    So, the total current passing through the circuit is:

    ITotal = I + I = 2I

    By Ohm's Law, the total current passing through the circuit is given by:

    ITotal = VTotal / RTotal

    Where VTotal is the voltage applied to the circuit.

    Therefore, the voltage applied to the circuit is:

    VTotal = ITotal * RTotal = 2I * (2RC + R) = 4IRC + 2IR

    Now, let's consider the voltage drop across each galvanometer:

    V1 = I * RC
    V2 = I * RC

    Since the galvanometers are identical, the voltage drop across each galvanometer is the same:

    V1 = V2 = V

    The voltage applied to the circuit is the sum of the voltage drops across the galvanometers and the resistor:

    VTotal = V + V + IR = 2V + IR

    Comparing this with the expression we obtained for VTotal earlier:

    2V + IR = 4IRC + 2IR

    Simplifying the equation:

    2V = 4IRC
    V = 2IRC

    So, the voltage drop across each galvanometer is equal to 2 times the internal resistance of the galvanometer multiplied by the current passing through the circuit.

    In conclusion, the voltage drop across each galvanometer is equal to 2 times the internal resistance of the galvanometer multiplied by the current passing through the circuit.

    Pragraph 2
    Consider an evacuated cylindrical chamber of height h having rigid conducting plates at the ends and an insulating curved surface as shown in the figure. A number of spherical balls made of a light weight and soft material and coated with a conducting material are placed on the bottom plate. The balls have a radius r << h. Now a high voltage source (HV) is connected across the conducting plates such that the bottom plate is at +V0 and the top plate at –V0. Due to their conducting surface, the balls will get charged, will become equipotential with the plate and are repelled by it. The balls will eventually collide with the top plate, where the coefficient of restitution can be taken to be zero due to the soft nature of the material of the balls. The electric field in the chamber can be considered to be that of a parallel plate capacitor. Assume that there are no collisions between the balls and the interaction between them is negligible. (Ignore gravity)
    Q. Which one of the following statements is correct?
    • a)
      The balls will bounce back to the bottom plate carrying the opposite charge they went up with
    • b)
      The balls will execute simple harmonic motion between the two plates
    • c)
      The balls will bounce back to the bottom plate carrying the same charge they went up with
    • d)
      The balls will stick to the top plate and remain there
    Correct answer is option 'A'. Can you explain this answer?

    Rajiv Reddy answered
    After hitting the top plate, the balls will get negatively charged and will now get attracted to the bottom plate which is positively charged. The motion of the balls will be periodic but not SHM.

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