A 0. 00 20 m aqueous solution of an ionic compound Co(NH3)5(NO2)Cl fre...
The freezing point of a solution is determined by the concentration of solute particles in the solution. In this case, the solute particles are the ions from the ionic compound Co(NH3)5(NO2)Cl.
To calculate the freezing point of the solution, we need to know the van't Hoff factor (i), which represents the number of particles that a solute molecule dissociates into in solution.
In this case, Co(NH3)5(NO2)Cl dissociates into Co2+, 5 NH3, NO2-, and Cl-. So the van't Hoff factor (i) is 7.
The freezing point depression (ΔTf) can be calculated using the formula:
ΔTf = i * Kf * m
Where:
ΔTf = freezing point depression
i = van't Hoff factor
Kf = cryoscopic constant of the solvent
m = molality of the solution
Since the solution is aqueous, the Kf value for water is used. The Kf value for water is 1.86 °C/m.
Given that the molality (m) of the solution is 0.020 m, we can calculate the freezing point depression:
ΔTf = 7 * 1.86 °C/m * 0.020 m
ΔTf = 0.2604 °C
Therefore, the freezing point of the 0.020 m aqueous solution of Co(NH3)5(NO2)Cl would be lowered by 0.2604 °C.