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Which of the following compounds would exhibit coordination isomerism?
a)[Cr(NH3)6][Co(CN)6]
b)[Cr(H2O)6]CI2
c) [Cr(en)3](NO2)3
d) [Ni(NH3)6][BF4]2
Correct answer is option 'A'. Can you explain this answer?
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Which of the following compounds would exhibit coordination isomerism?...
S-atom is donor in SCN and N-atom is donor in NCS. The linkage isomerism arises when ligand has two possibilities to attch on central atom.
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Which of the following compounds would exhibit coordination isomerism?...
Coordination Isomerism:
Coordination isomerism is a type of isomerism that occurs when the ligands and the metal ion in a coordination compound exchange positions between each other. In other words, the ligands that were originally coordinated to one metal ion are now coordinated to a different metal ion, and vice versa.

Analysis of the given options:
a) [Cr(NH3)6][Co(CN)6]
b) [Cr(H2O)6]Cl2
c) [Cr(en)3](NO2)3
d) [Ni(NH3)6][BF4]2

Explanation:
In order for a compound to exhibit coordination isomerism, it must contain two different metal ions that can exchange ligands. Let's analyze each option to determine if it fits this criteria.

a) [Cr(NH3)6][Co(CN)6]:
This compound contains two different metal ions, chromium (Cr) and cobalt (Co). The ligands, ammonia (NH3) and cyanide (CN), can potentially exchange between the two metal ions, leading to coordination isomerism.

b) [Cr(H2O)6]Cl2:
This compound contains only one metal ion, chromium (Cr). There is no possibility for ligand exchange between different metal ions.

c) [Cr(en)3](NO2)3:
This compound contains only one metal ion, chromium (Cr). There is no possibility for ligand exchange between different metal ions.

d) [Ni(NH3)6][BF4]2:
This compound contains only one metal ion, nickel (Ni). There is no possibility for ligand exchange between different metal ions.

Conclusion:
Based on the analysis, the compound [Cr(NH3)6][Co(CN)6] is the only one that contains two different metal ions (chromium and cobalt) and can exhibit coordination isomerism. The ligands, ammonia and cyanide, can potentially exchange between the two metal ions in this compound.
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Which of the following compounds would exhibit coordination isomerism?a)[Cr(NH3)6][Co(CN)6]b)[Cr(H2O)6]CI2c) [Cr(en)3](NO2)3d) [Ni(NH3)6][BF4]2Correct answer is option 'A'. Can you explain this answer?
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Which of the following compounds would exhibit coordination isomerism?a)[Cr(NH3)6][Co(CN)6]b)[Cr(H2O)6]CI2c) [Cr(en)3](NO2)3d) [Ni(NH3)6][BF4]2Correct answer is option 'A'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Which of the following compounds would exhibit coordination isomerism?a)[Cr(NH3)6][Co(CN)6]b)[Cr(H2O)6]CI2c) [Cr(en)3](NO2)3d) [Ni(NH3)6][BF4]2Correct answer is option 'A'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following compounds would exhibit coordination isomerism?a)[Cr(NH3)6][Co(CN)6]b)[Cr(H2O)6]CI2c) [Cr(en)3](NO2)3d) [Ni(NH3)6][BF4]2Correct answer is option 'A'. Can you explain this answer?.
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