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Which one of the following characteristics of the transition metals is associated with their catalytic activity? [2003]
  • a)
    Variable oxidation states
  • b)
    High enthalpy of atomization
  • c)
    Parmagnetic behaviour
  • d)
    Colour of hydrated ions
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Which one of the following characteristics of the transition metals is...
Transition metals have the ability to utilize (n –1)d -orbitals. Thus variable oxidation states enables the transition element to associate with the reactants in different forms.
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Which one of the following characteristics of the transition metals is...
Answer:

Variable oxidation states:
- Transition metals have the ability to exhibit multiple oxidation states due to the presence of incompletely filled d orbitals.
- This property allows them to easily gain or lose electrons during chemical reactions, making them excellent catalysts.
- The variable oxidation states of transition metals enable them to participate in redox reactions, where they can both accept and donate electrons.
- This ability to change oxidation states is crucial for many catalytic processes, as it allows the transition metal to readily switch between different forms, facilitating the reaction.

Explanation:
Transition metals are known for their catalytic activity, which is the ability to increase the rate of a chemical reaction without being consumed in the process. This is due to their unique electronic structure, specifically the presence of incompletely filled d orbitals.

The variable oxidation states of transition metals arise from the fact that d orbitals can hold different numbers of electrons. In a transition metal atom, the d orbitals can be either completely filled or partially filled, depending on the number of electrons present. This allows the transition metal to readily gain or lose electrons, leading to the formation of different oxidation states.

The ability to change oxidation states is crucial for catalytic activity. In a catalytic reaction, the transition metal acts as a catalyst by providing an alternative reaction pathway with lower activation energy. This lowers the energy barrier for the reaction, allowing it to proceed at a faster rate. The transition metal catalyst can undergo reversible oxidation and reduction reactions, enabling it to interact with reactant molecules and facilitate the reaction.

For example, in the Haber-Bosch process, which is used to produce ammonia from nitrogen and hydrogen, iron is commonly used as a catalyst. Iron can exist in different oxidation states, such as Fe2+ and Fe3+, and can readily switch between these states during the reaction. This allows the iron catalyst to interact with both nitrogen and hydrogen molecules, facilitating the formation of ammonia.

In summary, the variable oxidation states of transition metals are associated with their catalytic activity. This property allows transition metals to participate in redox reactions and easily gain or lose electrons, enabling them to act as catalysts in a wide range of chemical reactions.
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Read the passage given below and answer the following questions:The d block elements are the 40 elements contained in the four rows of ten columns (3-12) in the periodic table. As all the d block elements are metallic, the term d-block metals is synonymous. This set of d-block elements is also often identified as the transition metals, but sometimes the group 12 elements (zinc, cadmium, mercury) are excluded from the transition metals as the transition elements are defined as those with partly filled d or f shells in their compounds. Inclusion of the elements zinc, cadmium and mercury is necessary as some properties of the group 12 elements are appropriate logically to include with a discussion of transition metal chemistry. The term transition element or transition metal appeared to derive from early studies of periodicity such as the Mendeleev periodic table of the elements. His horizontal table of the elements was an attempt to group the elements together so that the chemistry of elements might be explained and predicted. In this table there are eight groups labeled I-VIII with each subdivided into A and B subgroups. Mendeleev recognized that certain properties of elements in Group VIII are related to those of some of the elements in Group VII and those at the start of the next row Group I. In that sense, these elements might be described as possessing properties transitional from one row of the table to the next.In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.Assertion (

Which one of the following characteristics of the transition metals is associated with their catalytic activity? [2003]a)Variable oxidation statesb)High enthalpy of atomizationc)Parmagnetic behaviourd)Colour of hydrated ionsCorrect answer is option 'A'. Can you explain this answer?
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