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The order of reaction with respect to OH minus is -1.The OH minus species (a) acts as catalyst (b) acts as indicator (c) acts as prohibitor (d) always appear in the chemical reaction?
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The order of reaction with respect to OH minus is -1.The OH minus spec...
The role of OH minus in a chemical reaction

OH minus (hydroxide ion) is a common species that can play different roles in a chemical reaction, depending on the specific reaction conditions. The order of reaction with respect to OH minus is -1, which means that the rate of the reaction is inversely proportional to the concentration of OH minus.

1. OH minus as a catalyst
OH minus can act as a catalyst in certain reactions by providing an alternative reaction pathway with lower activation energy. It can participate in the reaction and then regenerate itself, without being consumed in the overall reaction. The catalyst facilitates the reaction by lowering the energy barrier, allowing the reactants to convert into products more readily. In this case, OH minus affects the rate of the reaction but is not consumed during the process.

2. OH minus as an indicator
In some reactions, OH minus can act as an indicator to determine the endpoint or completion of a reaction. For example, in an acid-base titration, OH minus is used as a titrant to neutralize an acidic solution. The change in color or pH at the equivalence point indicates the completion of the reaction. However, OH minus is not directly involved in the rate-determining step of the reaction. Its role is solely to indicate the completion of the reaction.

3. OH minus as a prohibitor
OH minus can also act as a prohibitor or inhibitor in certain reactions, where it slows down or prevents the reaction from occurring. This can happen when OH minus reacts with a reactive intermediate or a reactive species, forming a stable complex that reduces the concentration of the reactive species available for further reaction. In this case, OH minus decreases the rate of the reaction by consuming reactive species and inhibiting the overall process.

4. Appearance of OH minus in a chemical reaction
The presence of OH minus in a chemical reaction depends on the reactants and reaction conditions. OH minus can be a product, reactant, or spectator ion depending on the specific reaction. It is important to consider the stoichiometry and the balanced equation of the reaction to determine whether OH minus appears or is consumed during the reaction.

Overall, the role of OH minus in a chemical reaction can vary depending on the specific reaction and conditions. It can act as a catalyst, indicator, prohibitor, or simply appear as a reactant or product. Understanding the specific role of OH minus in a reaction requires analyzing the reaction mechanism, stoichiometry, and reaction conditions.
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There are many reactions which obey a first order rate equation although it reality they are bi- or ter-molecular. As an example of these may be taken the decomposition of Carbonyl sulfide in water, namely, COS + H20 002 + H2SAccording to the law of mass action this reaction should be second order with the rate dependent on the concentration of both the carbonyl sulfide and the water. Actually however, the rate is found to be first order with respect to the carbonyl sulfide and independent of the water Reactions exhibiting such behaviour are said to be pseudo-molecular.The pseudo-unimoecuar nature of this reaction is explainable by the fact that water is present in such excess that its concentration remains practically constant during the course of the reaction. Under these condition b x = b, and the rate equation becomesOn integration this leads towhich is the equation for a first order reaction. It is evident, however, that the now constant k is not independent of the concentration, as is the case with true first order constants, but may vary with b if the latter is changed appreciably, When such is the case, the true constant k2 can be obtained from k by dividing the latter by b. pseudo-molecular reactions are encountered whenever one or more of the reactants remain constants during the course of an experiment. This is the case with reactions conducted in solvents which are themselves one of the reactants, as in the decomposition of carbonyl sulfide in water, or in the esterification of acetic anhydride in alcohol(CH3C0)20 + 2C2H5OH 2CH3C00C2H5 + H20Again, this is also true of reactions subject to catalysis, in which case the concentration of the catalyst does not change. The decomposition of diacetone alcohol to acetone in aqueous solution is catalysed by hydroxyl ions, with the rate proportional to the concentration of the alcohol and that of the base. Since the concentration of the base does not change within any one experiment, however, the rate equation reduces to one of first order with respect to the alcohol. But the rateconstant k obtained for various concentrations of base are not identical, as may be seen from table. To obtain from these the true second order velocity constant, the ks must be divided by the hydroxyl ion concentration. When this is done excellent k2 values result, as column 3 indicatesTable : Decomposition of diacetone alcohol in water at 25C (Catalyst : NaOH)Q.By what factor does the rate of reaction of diacetone alcohol in water solution change if p0H is increased by 2 units other things remaining same ?

The order of reaction with respect to OH minus is -1.The OH minus species (a) acts as catalyst (b) acts as indicator (c) acts as prohibitor (d) always appear in the chemical reaction?
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