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Excess of KI reacts with CuSO4 solution and then Na2S2O3 solution is added to it. Which of the statements is incorrect for this reaction ?
  • a)
    Na2S2O3 is oxidised
  • b)
    CuI2 is formed
  • c)
    Cu2I2 is formed
  • d)
    Evolved I2 is reduced
Correct answer is option 'B'. Can you explain this answer?
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Excess of KI reacts with CuSO4 solution and then Na2S2O3 solution is a...
Incorrect Statement: b) CuI2 is formed

Explanation:
- The given reaction involves the reaction between excess KI (potassium iodide) and CuSO4 (copper sulfate) solution followed by the addition of Na2S2O3 (sodium thiosulfate) solution.
- When excess KI is added to CuSO4 solution, a redox reaction takes place. Cu2+ ions in CuSO4 are reduced to Cu+ ions, while I- ions in KI are oxidized to I2 (elemental iodine).
- The overall reaction can be represented as follows:
CuSO4 + 2KI -> CuI2 + K2SO4

Analysis of the given options:
a) Na2S2O3 is oxidized:
- Na2S2O3 is a reducing agent and can undergo oxidation. However, in this reaction, Na2S2O3 is not oxidized. It acts as a reducing agent to reduce the CuI2 formed in the previous step.
- Na2S2O3 reduces CuI2 to form Cu2+ ions and I- ions.
- The reaction can be represented as follows:
CuI2 + 2Na2S2O3 -> 2Cu2+ + S4O6^2- + 2NaI

b) CuI2 is formed:
- This statement is incorrect. CuI2 is not formed in this reaction. Instead, CuI (copper(I) iodide) is formed.
- CuI is a yellow precipitate that forms when the Cu+ ions from CuSO4 react with the I- ions from excess KI.
- The reaction can be represented as follows:
2Cu+ + 4I- -> 2CuI

c) Cu2I2 is formed:
- This statement is correct. Cu2I2 (copper(II) iodide) is formed as a result of the reaction between CuI and I2.
- CuI reacts with I2 to form Cu2I2, which is a white precipitate.
- The reaction can be represented as follows:
2CuI + I2 -> Cu2I2

d) Evolved I2 is reduced:
- This statement is correct. The I2 that is evolved during the reaction is reduced by Na2S2O3.
- Na2S2O3 acts as a reducing agent and reduces I2 to I- ions.
- The reaction can be represented as follows:
I2 + 2Na2S2O3 -> 2NaI + Na2S4O6

In conclusion, the incorrect statement in this reaction is b) CuI2 is formed. The correct product formed is CuI (copper(I) iodide).
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Excess of KI reacts with CuSO4 solution and then Na2S2O3 solution is added to it. Which of the statements is incorrect for this reaction ?a)Na2S2O3 is oxidisedb)CuI2 is formedc)Cu2I2 is formedd)Evolved I2 is reducedCorrect answer is option 'B'. Can you explain this answer? for JEE 2025 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Excess of KI reacts with CuSO4 solution and then Na2S2O3 solution is added to it. Which of the statements is incorrect for this reaction ?a)Na2S2O3 is oxidisedb)CuI2 is formedc)Cu2I2 is formedd)Evolved I2 is reducedCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for JEE 2025 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Excess of KI reacts with CuSO4 solution and then Na2S2O3 solution is added to it. Which of the statements is incorrect for this reaction ?a)Na2S2O3 is oxidisedb)CuI2 is formedc)Cu2I2 is formedd)Evolved I2 is reducedCorrect answer is option 'B'. Can you explain this answer?.
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