In a canonical ensembleSelect one or more:a)the energy and temperature...
In a canonical ensemble, system can exchange only energy with environment.
Number of particles remains constant, also volume of the system remains constant. Therefore, temperature and density of system are constant.
The correct answers are: temperature is constant, density is constant
View all questions of this test
In a canonical ensembleSelect one or more:a)the energy and temperature...
The correct answers are option B and C: temperature is constant and density is constant in a canonical ensemble.
Explanation:
Canonical ensemble:
The canonical ensemble is a statistical ensemble that describes a system in thermal equilibrium with a heat bath at a fixed temperature. It is commonly used to describe systems with a fixed number of particles at a constant temperature.
Temperature is constant:
In the canonical ensemble, the temperature is held constant. This means that the system is in thermal equilibrium with a heat bath at a fixed temperature. The temperature determines the average energy of the particles in the system. In the canonical ensemble, the energy of the system can fluctuate, but the average energy remains constant.
Density is constant:
In the canonical ensemble, the density of the system is also held constant. Density refers to the number of particles per unit volume. In the canonical ensemble, the number of particles in the system is fixed, so the density remains constant.
Energy is not constant:
Contrary to option A, the energy of the system in the canonical ensemble is not constant. The energy can fluctuate due to thermal fluctuations, but the average energy remains constant. This is because the system is in thermal equilibrium with a heat bath at a fixed temperature.
Entropy is not constant:
Contrary to option D, the entropy of the system in the canonical ensemble is not constant. The entropy can fluctuate due to thermal fluctuations. In fact, the canonical ensemble is used to calculate the probability distribution of different energy states, which is related to the entropy of the system.
In summary, the correct answers are option B and C. In the canonical ensemble, the temperature is held constant and the density of the system remains constant. The energy of the system can fluctuate, but the average energy remains constant. The entropy of the system can also fluctuate due to thermal fluctuations.