pH of Ba(OH)2 solution is 12. Number of millimoles present in 100 mL o...
PH of Ba(OH)2 solution is 12. Number of millimoles present in 100 mL of Ba(OH)2 solution is:
To find the number of millimoles present in the solution, we need to first understand the concept of pH and the dissociation of Ba(OH)2.
1. Understanding pH:
pH is a measure of the acidity or alkalinity of a solution. It is defined as the negative logarithm of the hydrogen ion concentration ([H+]) in the solution. The pH scale ranges from 0 to 14, where pH 7 is considered neutral, pH less than 7 is acidic, and pH greater than 7 is alkaline.
2. Dissociation of Ba(OH)2:
Ba(OH)2 is a strong base that dissociates completely in water. It can be represented by the following equation:
Ba(OH)2 -> Ba2+ + 2OH-
This means that for every mole of Ba(OH)2, 1 mole of Ba2+ ions and 2 moles of OH- ions are produced.
3. Relationship between pH and pOH:
Since Ba(OH)2 is a strong base, it dissociates completely into OH- ions. The concentration of OH- ions can be used to calculate the pOH of the solution, which is related to pH by the equation:
pH + pOH = 14
Given that the pH of the Ba(OH)2 solution is 12, we can calculate the pOH as follows:
pOH = 14 - pH = 14 - 12 = 2
4. Calculating the concentration of OH- ions:
The pOH can be used to calculate the concentration of OH- ions using the equation:
pOH = -log[OH-]
2 = -log[OH-]
10^-2 = [OH-]
Therefore, the concentration of OH- ions in the solution is 0.01 M.
5. Calculating the number of millimoles:
The concentration of OH- ions is given in moles per liter (M). To convert it to millimoles per milliliter (mM), we need to multiply by the volume of the solution.
Concentration of OH- ions = 0.01 M
Volume of solution = 100 mL = 0.1 L
Number of millimoles = Concentration x Volume in milliliters
Number of millimoles = 0.01 M x 0.1 L x 1000 mL/L = 1 mM
Therefore, the number of millimoles present in 100 mL of Ba(OH)2 solution is 1 mM.
Hence, option 'A' is the correct answer.