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Among the following boron hydrides which of the following is highest bronsted acidity :
  • a)
    B5 H9
  • b)
    B10H14
  • c)
    B6 H10
  • d)
    B4 H10
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Among the following boron hydrides which of the following is highest b...
As the number of boron atom increases in boron hydrides, it bronsted acidity also increases.
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Among the following boron hydrides which of the following is highest b...
Explanation:

In order to determine the Bronsted acidity of the boron hydrides, we need to consider the stability of the conjugate base formed after the loss of a proton (H+). The more stable the conjugate base, the stronger the acid.

B5H9:
B5H9 is a pentaborane compound with 5 boron atoms and 9 hydrogen atoms. After losing a proton, the conjugate base formed is B5H8-. The negative charge is shared among 5 boron atoms, resulting in a less stable structure. Therefore, B5H9 is not the most acidic among the options.

B10H14:
B10H14 is a decaborane compound with 10 boron atoms and 14 hydrogen atoms. After losing a proton, the conjugate base formed is B10H13-. The negative charge is shared among 10 boron atoms, resulting in a more stable structure compared to B5H9. This increased stability makes B10H14 more acidic than B5H9.

B6H10:
B6H10 is a boron hydride with 6 boron atoms and 10 hydrogen atoms. After losing a proton, the conjugate base formed is B6H9-. The negative charge is shared among 6 boron atoms, similar to B10H14. However, B6H10 is less acidic than B10H14 due to the increased steric hindrance caused by the larger boron cluster.

B4H10:
B4H10 is a boron hydride with 4 boron atoms and 10 hydrogen atoms. After losing a proton, the conjugate base formed is B4H9-. The negative charge is shared among 4 boron atoms, resulting in a more stable structure compared to B5H9. However, B4H10 is less acidic than B10H14 and B6H10 due to the decreased number of boron atoms.

Conclusion:
Among the given options, B10H14 is the most acidic boron hydride. This is because the conjugate base formed after the loss of a proton is the most stable among the options, with the negative charge being shared among 10 boron atoms.
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Among the following boron hydrides which of the following is highest bronsted acidity :a)B5H9b)B10H14c)B6H10d)B4H10Correct answer is option 'B'. Can you explain this answer?
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