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Crystal field splitting energy Δ0 for [ Cr (NH3)6]2+ is 10200 cm-1. The Δt for [Cr(NH3)4]2+ is ___________cm-1.
Correct answer is between '4525,4535'. Can you explain this answer?
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Crystal field splitting energyΔ0 for [ Cr (NH3)6]2+ is10200 cm-1...
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Crystal field splitting energyΔ0 for [ Cr (NH3)6]2+ is10200 cm-1...
The crystal field splitting energy (Δ) is the energy difference between the two sets of d orbitals in a metal ion in a crystal field. In a crystal field, the degeneracy (equal energy) of the d orbitals is lifted due to the presence of ligands surrounding the metal ion.
The splitting energy depends on the geometry of the ligand field and the metal ion's electronic configuration. In octahedral coordination complexes, the d orbitals split into two sets: the lower energy set (eg orbitals) and the higher energy set (t2g orbitals). The energy difference between these two sets is denoted by Δo.
In tetrahedral coordination complexes, the d orbitals also split into two sets, but the energy difference is smaller than in octahedral complexes. The energy difference between these two sets is denoted by Δt.
The crystal field splitting energy determines the color and magnetic properties of transition metal complexes. It affects the absorption of light and the energy levels of the d electrons, which in turn influences the electronic and magnetic properties of the complex.
The splitting energy depends on the geometry of the ligand field and the metal ion's electronic configuration. In octahedral coordination complexes, the d orbitals split into two sets: the lower energy set (eg orbitals) and the higher energy set (t2g orbitals). The energy difference between these two sets is denoted by Δo.
In tetrahedral coordination complexes, the d orbitals also split into two sets, but the energy difference is smaller than in octahedral complexes. The energy difference between these two sets is denoted by Δt.
The crystal field splitting energy determines the color and magnetic properties of transition metal complexes. It affects the absorption of light and the energy levels of the d electrons, which in turn influences the electronic and magnetic properties of the complex.
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Crystal field splitting energyΔ0 for [ Cr (NH3)6]2+ is10200 cm-1. The Δt for [Cr(NH3)4]2+is ___________cm-1.Correct answer is between '4525,4535'. Can you explain this answer?
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