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The resistance of 0.01N solution of an electrolyte AB at 328K is 100 ohm. The specific conductance of solution is (cell constant = 1cm-1) -
  • a)
    100 ohm
  • b)
    10-2 ohm-1 
  • c)
    10-2 ohm-1 cm-1
  • d)
    102 ohm-cm
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
The resistance of 0.01N solution of an electrolyte AB at 328K is 100 o...
Specific conductance is defined as the conductance of a material or solution occupying one cm^3 volume.
Moreover, Specific conductance, K is inversely proportional to resistance
i.e., K = Cell constant /R
= 1 cm^-1 / 100 = 10^-2 ohm^-1cm^-1
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The resistance of 0.01N solution of an electrolyte AB at 328K is 100 o...
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The resistance of 0.01N solution of an electrolyte AB at 328K is 100 o...
Given:
- Resistance of 0.01N solution of electrolyte AB at 328K = 100 ohm
- Cell constant = 1 cm^-1

To find:
Specific conductance of the solution

Formula:
Specific conductance (κ) = Conductivity (σ) × Cell constant (C)

Explanation:

The specific conductance of a solution is a measure of its ability to conduct electricity. It is defined as the conductance of a solution of unit volume (1 cm^3) and unit area of cross-section (1 cm^2).

We are given the resistance of the solution, which can be used to calculate the conductivity using Ohm's Law.

Step 1: Calculation of Conductivity
Using Ohm's Law:
Resistance (R) = ρ × (L/A), where ρ is the resistivity, L is the length of the conductor, and A is the cross-sectional area.

In this case, the resistance (R) is given as 100 ohm, and the length (L) and cross-sectional area (A) are not given. However, since the cell constant (C) is given as 1 cm^-1, we can assume that the length and cross-sectional area are both equal to 1 cm.

So, the resistivity (ρ) can be calculated as:
ρ = R × (A/L) = 100 ohm × (1 cm/1 cm) = 100 ohm × 1 = 100 ohm-cm

The conductivity (σ) is the reciprocal of resistivity:
σ = 1/ρ = 1/100 ohm-cm = 0.01 ohm^-1-cm^-1

Step 2: Calculation of Specific Conductance
Using the formula:
Specific conductance (κ) = Conductivity (σ) × Cell constant (C)
κ = 0.01 ohm^-1-cm^-1 × 1 cm^-1 = 0.01 ohm^-1-cm^-1

Answer:
The specific conductance of the 0.01N solution of electrolyte AB at 328K is 0.01 ohm^-1-cm^-1. Option C is the correct answer.
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