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Bond lengths and angles have been determined by gas phase electron diffraction for two similar complexes, Fe(CO)4(C2H4)(X) and fe(CO)4(C2F4), (Y)

Which of the following statement is true
  • a)
    Data(I) is given for (Y) 
  • b)
    Data (I) is given for (X)
  • c)
    Both (X) and (Y) have data (I)
  • d)
    Both (X) and (Y) have data (II)
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Bond lengths and angles have been determined by gas phase electron dif...
As C2F4 is strong -acceptor than C2H4. Hence, there will be more backbonding in (Y). Hence, C–C bond will be larger and M–C bond will be shorter in Y.
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Bond lengths and angles have been determined by gas phase electron diffraction for two similar complexes, Fe(CO)4(C2H4)(X) and fe(CO)4(C2F4), (Y)Which of the following statement is truea)Data(I) is given for (Y)b)Data (I) is given for (X)c)Both (X) and (Y) have data (I)d)Both (X) and (Y) have data (II)Correct answer is option 'A'. Can you explain this answer?
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