A particle is confined to a 1 D box of length 1mm.if the length is cha...
Explanation:
1 D Box: A one-dimensional box is a hypothetical particle in a box with only one degree of freedom, which can move along a straight line.
Ground State Energy: The energy of the particle in the lowest possible energy state is known as the ground state energy.
Formula: The ground state energy of a 1D box is given by the formula E1= h^2/8mL^2.
Given: Length of 1D box, L = 1mm, Change in length, ΔL = 10^-12m, we need to find the % change in ground state energy.
Solution:
Let's calculate the initial ground state energy, E1.
E1 = h^2/8mL^2
Where h = Planck's constant, m = mass of the particle.
We assume that the particle is an electron.
h = 6.626 x 10^-34 J.s
m = 9.109 x 10^-31 kg
L = 1mm = 10^-3 m
E1 = (6.626 x 10^-34)^2/(8 x 9.109 x 10^-31 x (10^-3)^2) = 1.639 x 10^-18 J
Now, let's calculate the new ground state energy, E2.
We know that the length of the box has changed by ΔL = 10^-12m.
So, the new length of the box, L' = L + ΔL = 1mm + 10^-12m = 1.000000000001mm
L' = 1.000000000001mm = (1 + 10^-12)mm
E2 = h^2/8m(L')^2
E2 = (6.626 x 10^-34)^2/(8 x 9.109 x 10^-31 x (1.000000000001 x 10^-3)^2) = 1.642 x 10^-18 J
The % change in ground state energy is given by the formula:
% Change = |(E2 - E1)/E1| x 100
% Change = |(1.642 x 10^-18 - 1.639 x 10^-18)/1.639 x 10^-18| x 100 = 2 x 10^-4 %
Therefore, the % change in ground state energy is 2 x 10^-4 %.