Chemistry Exam  >  Chemistry Questions  >  Among the following complexes, the ones that ... Start Learning for Free
Among the following complexes, the ones that show(s) optical activity are:
I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III  = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-
  • a)
    I       
  • b)
    II                               
  • c)
    III       
  • d)
    IV ​
Correct answer is option 'A,B,D'. Can you explain this answer?
Most Upvoted Answer
Among the following complexes, the ones that show(s) optical activity ...
To determine which complexes show optical activity, we need to consider the presence of chiral centers and symmetry elements.

I = [Ru(bipyridyl)3]
II = [Cr(EDTA)]-
III = trans[Cr(Cl)2(oxalate)2]3-
IV = cis[Cr(Cl)2(oxalate)2]3-

I. [Ru(bipyridyl)3]
This complex contains a central metal ion (Ru) bonded to three bipyridyl ligands. The bipyridyl ligands are not chiral, and the complex does not possess any chiral centers. Therefore, complex I does not show optical activity.

II. [Cr(EDTA)]-
This complex contains a central metal ion (Cr) bonded to the EDTA ligand. The EDTA ligand is chelating and forms a six-membered ring with the metal ion. The complex does not possess any chiral centers, and there are no symmetry elements that can lead to optical activity. Therefore, complex II does not show optical activity.

III. trans[Cr(Cl)2(oxalate)2]3-
This complex contains a central metal ion (Cr) bonded to two chloride ions and two oxalate ligands. The oxalate ligand is chelating and forms a six-membered ring with the metal ion. The complex possesses a chiral center due to the presence of the oxalate ligands. However, the trans configuration suggests that the two chiral centers cancel each other out, resulting in an overall achiral complex. Therefore, complex III does not show optical activity.

IV. cis[Cr(Cl)2(oxalate)2]3-
This complex contains a central metal ion (Cr) bonded to two chloride ions and two oxalate ligands. The oxalate ligand is chelating and forms a six-membered ring with the metal ion. The complex possesses a chiral center due to the presence of the oxalate ligands. The cis configuration suggests that the two chiral centers do not cancel each other out, resulting in an overall chiral complex. Therefore, complex IV shows optical activity.

In summary, the complexes that show optical activity are:

a) I
b) II
d) IV
Explore Courses for Chemistry exam
Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer?
Question Description
Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer?.
Solutions for Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer? in English & in Hindi are available as part of our courses for Chemistry. Download more important topics, notes, lectures and mock test series for Chemistry Exam by signing up for free.
Here you can find the meaning of Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer?, a detailed solution for Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer? has been provided alongside types of Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Among the following complexes, the ones that show(s) optical activity are:I = [Ru(bipyridyl)3]+, II = [Cr(EDTA)]-, III = trans[Cr(Cl)2(oxalate)2]3-, IV = cis[Cr(Cl)2(oxalate)2]3-a)I b)II c)IIId)IV ​Correct answer is option 'A,B,D'. Can you explain this answer? tests, examples and also practice Chemistry tests.
Explore Courses for Chemistry exam
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev