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Oxidation of toluene with CrO3 in the presence of (CH3CO)2O gives a product (A) which on treatment with aqueous NaOH produces
  • a)
    C6H5CHO
  • b)
    (C6H5CO)2O
  • c)
    C6H5COONa
  • d)
    None of these
Correct answer is option 'A'. Can you explain this answer?
Most Upvoted Answer
Oxidation of toluene with CrO3 in the presence of (CH3CO)2O gives a pr...
Correct answer is (C)
This is not etard's reaction but similar to that because reaction of Toluene with CrO3 and acetic anhydride gives Benzaldehyde on further reaction of benzaldehyde with NaoH gives Sodium benzoate i.e,C6H5COONa.This is called cannizzaro rxn.
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Oxidation of toluene with CrO3 in the presence of (CH3CO)2O gives a pr...
Explanation:

The oxidation of toluene with CrO3 in the presence of (CH3CO)2O is known as the Etard reaction. This reaction is a powerful method for converting aromatic compounds into the corresponding carbonyl compounds.

Etard Reaction:
1. Toluene is oxidized by CrO3 in the presence of (CH3CO)2O to form a product (A).
2. The product (A) is then treated with aqueous NaOH to form the final product.

Step 1: Oxidation of Toluene:
The oxidation of toluene with CrO3 in the presence of (CH3CO)2O leads to the formation of a product (A). The (CH3CO)2O acts as an oxidizing agent and CrO3 acts as a catalyst in this reaction. The reaction can be represented as follows:

C6H5CH3 + CrO3 + (CH3CO)2O → Product (A)

Step 2: Treatment with Aqueous NaOH:
The product (A) obtained from the oxidation of toluene is then treated with aqueous NaOH. This treatment leads to the formation of the final product, which is a carbonyl compound.

Product (A) + NaOH → C6H5CHO + Na2CrO4 + (CH3COOH)

In this step, the NaOH acts as a base and converts the product (A) into the corresponding carbonyl compound, C6H5CHO (benzaldehyde). Na2CrO4 and (CH3COOH) are formed as byproducts of the reaction.

Conclusion:
The correct answer is option 'A', which represents the formation of benzaldehyde (C6H5CHO) as the final product in the given reaction.
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Oxidation of toluene with CrO3 in the presence of (CH3CO)2O gives a product (A) which on treatment with aqueous NaOH producesa) C6H5CHO b) (C6H5CO)2O c) C6H5COONa d) None of these Correct answer is option 'A'. Can you explain this answer?
Question Description
Oxidation of toluene with CrO3 in the presence of (CH3CO)2O gives a product (A) which on treatment with aqueous NaOH producesa) C6H5CHO b) (C6H5CO)2O c) C6H5COONa d) None of these Correct answer is option 'A'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Oxidation of toluene with CrO3 in the presence of (CH3CO)2O gives a product (A) which on treatment with aqueous NaOH producesa) C6H5CHO b) (C6H5CO)2O c) C6H5COONa d) None of these Correct answer is option 'A'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Oxidation of toluene with CrO3 in the presence of (CH3CO)2O gives a product (A) which on treatment with aqueous NaOH producesa) C6H5CHO b) (C6H5CO)2O c) C6H5COONa d) None of these Correct answer is option 'A'. Can you explain this answer?.
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