An optically active hydrocarbon X has molecular formula C6H12. X on ca...
The optically active C6H1 2 hydrocarbon is 3-Methylpent-1-ene, having one chiral carbon shown in fig A.
On catalytic hydrogenation , the compound obtained is shown in fig B, and the molecule does not have chiral carbon.
The reaction is C6H1 2 → C6H1 4 and this reaction takes place inthe presence of H2 and Pd.
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An optically active hydrocarbon X has molecular formula C6H12. X on ca...
Optically Active Hydrocarbon X
Molecular Formula: C6H12
Reaction: Catalytic Hydrogenation of X gives C6H14 (optically inactive)
Possible Structures:
a) 3-methyl-1-pentene
b) 3-methyl-2-pentene
c) 4-methyl-2-pentene
d) 2-ethyl-1-butene
Explanation:
1. Determining the Chiral Center:
To determine the optically active hydrocarbon X, we need to identify its chiral center. A chiral center is a carbon atom that is bonded to four different groups. In the given molecular formula C6H12, there are multiple possibilities for chiral centers.
2. Analyzing the Isomers:
a) 3-methyl-1-pentene:
In this isomer, the carbon atom attached to the methyl group is bonded to two different alkyl groups (ethyl and butyl). Therefore, it can be a potential chiral center.
b) 3-methyl-2-pentene:
In this isomer, the carbon atom attached to the methyl group is bonded to two ethyl groups. This carbon atom cannot be a chiral center as it is bonded to two identical groups.
c) 4-methyl-2-pentene:
In this isomer, the carbon atom attached to the methyl group is bonded to two ethyl groups. This carbon atom cannot be a chiral center as it is bonded to two identical groups.
d) 2-ethyl-1-butene:
In this isomer, the carbon atom attached to the ethyl group is bonded to two different alkyl groups (methyl and butyl). Therefore, it can be a potential chiral center.
3. Chiral Carbon in 3-methyl-1-pentene:
The isomer 3-methyl-1-pentene has a chiral carbon atom as discussed earlier. Since the catalytic hydrogenation of X gives an optically inactive compound, it indicates the presence of a chiral center in X. Therefore, the correct answer is option 'A' - 3-methyl-1-pentene.
Conclusion:
The optically active hydrocarbon X with the molecular formula C6H12 can be identified as 3-methyl-1-pentene. The presence of a chiral center in this compound leads to its optical activity.
An optically active hydrocarbon X has molecular formula C6H12. X on ca...
Compound F has the molecular formula C5H8 and is optically active. On catalytic hydrogenation F yeilds G(C5H12) is optically inactive. Propose structures for F and G.