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JEE Exam  >  JEE Questions  >  The compound(s) with TWO lone pairs of electr... Start Learning for Free
The compound(s) with TWO lone pairs of electrons on the central atom is(are)
  • a)
    BrF5
  • b)
    ClF3
  • c)
    XeF4
  • d)
    SF4
Correct answer is option 'B,C'. Can you explain this answer?
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Most Upvoted Answer
The compound(s) with TWO lone pairs of electrons on the central atom i...
ClF3 and XeF4: Compounds with Two Lone Pairs of Electrons
ClF3 and XeF4 are the compounds that have two lone pairs of electrons on the central atom. Let's discuss why these two compounds fit this description.

ClF3 (Chlorine Trifluoride)
- In ClF3, the central atom is chlorine (Cl).
- Chlorine has 7 valence electrons, and in ClF3, it forms three single bonds with fluorine atoms.
- The three bond pairs and two lone pairs on the chlorine atom make a total of five electron pairs around the central atom.
- This arrangement results in two lone pairs of electrons on the central chlorine atom, making ClF3 a compound with two lone pairs.

XeF4 (Xenon Tetrafluoride)
- In XeF4, the central atom is xenon (Xe).
- Xenon has 8 valence electrons, and in XeF4, it forms four single bonds with fluorine atoms.
- The four bond pairs and two lone pairs on the xenon atom make a total of six electron pairs around the central atom.
- This arrangement results in two lone pairs of electrons on the central xenon atom, making XeF4 a compound with two lone pairs.

Conclusion
- ClF3 and XeF4 are the compounds that have two lone pairs of electrons on the central atom.
- The presence of lone pairs affects the geometry and properties of these compounds.
- Understanding the electron pair geometry is essential in predicting the molecular shape and reactivity of these compounds.
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Community Answer
The compound(s) with TWO lone pairs of electrons on the central atom i...
CIF3 abd XeF4 contain two lone pair of electrons on the central atom.
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Valence shell electron-pair repulsion theory predicts the shape of a molecule by considering the most stable configuration of the bond angles in the molecule. The main points of the theory are(i) Electron pairs in the valence shell of central atom of a molecule, whether bonding or lone pairs are regarded as occupying localised orbitals. These orbitals arrange themselves so as to minimize the mutual electronic repulsions.(ii) The magnitude of the different types of electronic repulsions follow the order given below:Lone pair-lone pair> lone pair-bonding pair > bonding pair-bonding pair. These repulsive forces alter the bond angles of the molecule or ion.(iii) The electron repulsion between two pairs of electrons will be minimum if they stay as far as possible. On this basis, several studied. have been doneWhich of the following statements is correct ?

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The compound(s) with TWO lone pairs of electrons on the central atom is(are)a)BrF5b)ClF3c)XeF4d)SF4Correct answer is option 'B,C'. Can you explain this answer?
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