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Which of the following is/are correct for an ideal binary solution of two volatile liquids (eg. benzene and toluene)? 
  • a)
    its vapour is always richer in the more volatile component (compared to the liquid).
  • b)
    the liquid will gradually become richer in the less volatile component if such a mixture is boiled (distilled).
  • c)
    the pT (ie. the total pressure) above the solution will be the sum of the vapour pressures of the two pure components.
  • d)
    the boiling point of the solution will be less than the boiling points of the two components. 
Correct answer is option 'A,B'. Can you explain this answer?
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Ideal Binary Solution of Two Volatile Liquids

An ideal binary solution of two volatile liquids refers to a mixture of two liquids that obey Raoult's law.

Raoult's Law

Raoult's law states that the partial pressure of each component of an ideal mixture of liquids is directly proportional to its mole fraction in the solution.

a) Vapor Richer in More Volatile Component

For an ideal binary solution, the vapour is always richer in the more volatile component compared to the liquid. This is because the more volatile component has a higher vapour pressure, and hence, it evaporates faster and in greater amounts.

b) Gradual Enrichment of Liquid

If such a mixture is boiled or distilled, the liquid will gradually become richer in the less volatile component. This is because the less volatile component has a higher boiling point and hence, it takes longer to evaporate.

c) Total Pressure Above Solution

The pT (i.e. the total pressure) above the solution will be the sum of the vapour pressures of the two pure components. This is because each component contributes to the total pressure in proportion to its mole fraction in the solution.

d) Lower Boiling Point

The boiling point of the solution will be less than the boiling points of the two components. This is because the presence of the second component lowers the vapour pressure of the first component and reduces its boiling point.

Conclusion

In summary, an ideal binary solution of two volatile liquids obeys Raoult's law, and its vapour is always richer in the more volatile component. If such a mixture is boiled, the liquid will gradually become richer in the less volatile component. The total pressure above the solution is the sum of the vapour pressures of the two pure components, and the boiling point of the solution is lower than the boiling points of the two components.
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Which of the following is/are correct for an ideal binary solution of two volatile liquids (eg. benzene and toluene)?a)its vapour is always richer in the more volatile component (compared to the liquid).b)the liquid will gradually become richer in the less volatile component if such a mixture is boiled (distilled).c)the pT (ie. the total pressure) above the solution will be the sum of the vapour pressures of the two pure components.d)the boiling point of the solution will be less than the boiling points of the two components.Correct answer is option 'A,B'. Can you explain this answer?
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Which of the following is/are correct for an ideal binary solution of two volatile liquids (eg. benzene and toluene)?a)its vapour is always richer in the more volatile component (compared to the liquid).b)the liquid will gradually become richer in the less volatile component if such a mixture is boiled (distilled).c)the pT (ie. the total pressure) above the solution will be the sum of the vapour pressures of the two pure components.d)the boiling point of the solution will be less than the boiling points of the two components.Correct answer is option 'A,B'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Which of the following is/are correct for an ideal binary solution of two volatile liquids (eg. benzene and toluene)?a)its vapour is always richer in the more volatile component (compared to the liquid).b)the liquid will gradually become richer in the less volatile component if such a mixture is boiled (distilled).c)the pT (ie. the total pressure) above the solution will be the sum of the vapour pressures of the two pure components.d)the boiling point of the solution will be less than the boiling points of the two components.Correct answer is option 'A,B'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following is/are correct for an ideal binary solution of two volatile liquids (eg. benzene and toluene)?a)its vapour is always richer in the more volatile component (compared to the liquid).b)the liquid will gradually become richer in the less volatile component if such a mixture is boiled (distilled).c)the pT (ie. the total pressure) above the solution will be the sum of the vapour pressures of the two pure components.d)the boiling point of the solution will be less than the boiling points of the two components.Correct answer is option 'A,B'. Can you explain this answer?.
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