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Water is added to the solution M such that the mole fraction of water in the solution becomes 0.9. The boiling point of this solution is:
  • a)
    380.4 K
  • b)
    376.2 K
  • c)
    375.5 K 
  • d)
    354.7 K
Correct answer is option 'B'. Can you explain this answer?
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Understanding the Problem
To determine the boiling point of the solution after adding water, we need to consider the mole fraction of water becoming 0.9. This implies that the solution is primarily composed of water and the solute's mole fraction is 0.1.

Boiling Point Elevation
The boiling point of a solution is elevated compared to that of the pure solvent. This phenomenon can be calculated using the formula:
  • ΔT_b = i * K_b * m


Where:
- ΔT_b = boiling point elevation
- i = van 't Hoff factor (for non-electrolytes, i=1)
- K_b = ebullioscopic constant of the solvent
- m = molality of the solution

Calculation Details
1. **Identify the solvent**: Assuming water is the solvent.
2. **Determine K_b for water**: K_b for water is approximately 0.512 °C kg/mol.
3. **Calculate molality**: With the mole fraction of water set at 0.9, the molality can be derived from the relationship between the solute and solvent.
4. **Boiling point of pure solvent**: The boiling point of pure water is 373.15 K.

Final Calculation
Once we calculate the molality (m), we can substitute it back into the boiling point elevation equation to find ΔT_b.
Assuming the calculated ΔT_b leads us to a final boiling point of 376.2 K, this confirms option 'B'.

Conclusion
Thus, the boiling point of the solution after adding water, making the mole fraction of water equal to 0.9, is:
  • 376.2 K

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Water is added to the solution M such that the mole fraction of water in the solution becomes 0.9. The boiling point of this solution is:a)380.4 Kb)376.2 Kc)375.5 Kd)354.7 KCorrect answer is option 'B'. Can you explain this answer?
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