5 moles of oxygen is heated at constant volume from 10C to 20C tempera...
∆U = n × Cv × ∆T∆U = 5 × (5R/2) × (20-10)J∆U = 5×5×8.314×10/2 J∆U = 250 × 4.157 JNow 1J = 1/4.18 CalSo ∆U = 250 × 4.157 / 4.18∆U ≈ 250 cal
5 moles of oxygen is heated at constant volume from 10C to 20C tempera...
Change in Internal Energy of Gas
To determine the change in internal energy of the gas, we can use the equation:
ΔU = nCvΔT
Where:
ΔU is the change in internal energy
n is the number of moles of the gas
Cv is the molar heat capacity at constant volume
ΔT is the change in temperature
Gathering the Information
Given:
Number of moles of oxygen (n) = 5 moles
Change in temperature (ΔT) = 20°C - 10°C = 10°C
Understanding Molar Heat Capacity at Constant Volume (Cv)
Molar heat capacity at constant volume (Cv) is the amount of heat required to raise the temperature of one mole of a substance by one degree Celsius at constant volume. For an ideal gas, the molar heat capacity at constant volume is given by the equation:
Cv = (f/2)R
Where:
Cv is the molar heat capacity at constant volume
f is the degree of freedom of the gas molecules
R is the ideal gas constant
For a diatomic gas like oxygen, the degree of freedom (f) is equal to 5, which includes translational motion in three dimensions and rotational motion about two axes. Therefore, for oxygen gas, f = 5.
Calculating the Change in Internal Energy
Using the equation for the change in internal energy, we can substitute the given values:
ΔU = nCvΔT
ΔU = (5 moles) * ((5/2) * R) * (10°C)
Since R is a constant, we can simplify the equation further:
ΔU = (5/2) * R * 10 moles * °C
Conversion of Temperature to Kelvin
Before calculating the final value, we need to convert the temperature from Celsius to Kelvin because the ideal gas constant (R) is typically given in units of J/(mol·K). The conversion is done by adding 273.15 to the Celsius temperature:
10°C + 273.15 = 283.15 K
Now we can substitute the value of R and calculate the change in internal energy:
ΔU = (5/2) * R * 10 moles * 283.15 K
Calculating the Final Value
To obtain the final value, we need to know the numerical value of the ideal gas constant (R), which is 8.314 J/(mol·K):
ΔU = (5/2) * 8.314 J/(mol·K) * 10 moles * 283.15 K
Simplifying the equation further, we get:
ΔU = 5873.375 J
Therefore, the change in internal energy of the gas is approximately 5873.375 J.
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