Chemistry Exam  >  Chemistry Questions  >  Why in the IR spectrum of Benzoyl chloride, a... Start Learning for Free
Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?
  • a)
    Inductive effect
  • b)
    Fermi resonance between C = O band and first overtone
  • c)
    Conjugation effect
  • d)
    Hyperconjugation effect
Correct answer is option 'B'. Can you explain this answer?
Most Upvoted Answer
Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1...
The weak band near 1750 cm-1 in the IR spectrum of benzoyl chloride is formed due to Fermi resonance between the C=O band and the first overtone.

Explanation:
IR Spectrum and Benzoyl Chloride:
- The infrared (IR) spectrum is a useful tool in identifying functional groups in organic compounds.
- It shows the absorption of infrared light by the compound as a function of wavelength or frequency.
- Benzoyl chloride (C6H5COCl) is an organic compound with a benzene ring attached to a carbonyl group (C=O) and a chlorine atom (Cl).

Fermi Resonance:
- Fermi resonance occurs when two vibrational modes of a molecule are close in energy and interact with each other.
- In the case of benzoyl chloride, the carbonyl (C=O) stretching vibration is the primary mode of interest.
- The first overtone is the second harmonic of the original vibration, occurring at twice the frequency.
- In benzoyl chloride, the first overtone of the C=O stretching vibration is close in energy to the C-Cl stretching vibration.
- This close energy proximity leads to a Fermi resonance interaction between the two vibrations.

Effects of Fermi Resonance:
- Fermi resonance can result in the splitting or broadening of the absorption band in the IR spectrum.
- In the case of benzoyl chloride, the interaction between the C=O stretching vibration and the first overtone of the C-Cl stretching vibration causes the weak band near 1750 cm-1 to form.
- The interaction between the two vibrations redistributes the energy, resulting in the formation of a new absorption band.

Other Options:
- The inductive effect refers to the electron-withdrawing or electron-donating effects of nearby groups, but it does not explain the formation of the weak band in the IR spectrum.
- The conjugation effect refers to the delocalization of electrons in a molecule, but it is not directly related to the formation of the weak band.
- The hyperconjugation effect is a stabilizing interaction between a filled σ orbital and an adjacent empty or partially filled π orbital. It does not explain the formation of the weak band.

Conclusion:
The formation of the weak band near 1750 cm-1 in the IR spectrum of benzoyl chloride is best explained by Fermi resonance between the C=O band and the first overtone. This interaction between the two vibrations leads to the redistribution of energy and the formation of a new absorption band.
Free Test
Community Answer
Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1...
Benzoyl chloride

A weak band near 1750 cm-1. Since, band is of weak intensity, it must be due to fermi Resonance. So correct option is Fermi resonance between C = O band and first overtone.
Explore Courses for Chemistry exam
Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer?
Question Description
Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer?.
Solutions for Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer? in English & in Hindi are available as part of our courses for Chemistry. Download more important topics, notes, lectures and mock test series for Chemistry Exam by signing up for free.
Here you can find the meaning of Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer?, a detailed solution for Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer? has been provided alongside types of Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Why in the IR spectrum of Benzoyl chloride, a weak band near 1750 cm-1 is formed?a)Inductive effectb)Fermi resonance between C = O band and first overtonec)Conjugation effectd)Hyperconjugation effectCorrect answer is option 'B'. Can you explain this answer? tests, examples and also practice Chemistry tests.
Explore Courses for Chemistry exam
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev