What catalyst is used for oxidation of ammonia to produce nitric acid?...
Ammonia is oxidized to nitrogen (II) oxide in the presence of Pt/Rh gauze catalyst at a temperature of 500 K and a pressure of 9 bars. The nitrous oxide is then converted to nitrogen dioxide which is further reacted with water to produce nitric acid. The NO formed is recycled.
What catalyst is used for oxidation of ammonia to produce nitric acid?...
The catalyst used for the oxidation of ammonia to produce nitric acid is the Platinum-Rhodium gauze.
The process of ammonia oxidation to nitric acid is known as the Ostwald process, and it involves several steps. The catalyst plays a crucial role in facilitating the reaction and increasing its efficiency.
Here is a detailed explanation of why the Platinum-Rhodium gauze is used as the catalyst for this reaction:
1. The Ostwald process:
- The Ostwald process is a multi-step chemical reaction that converts ammonia (NH3) to nitric acid (HNO3).
- The first step involves the oxidation of ammonia to nitric oxide (NO) and water (H2O).
- The second step is the oxidation of nitric oxide to nitrogen dioxide (NO2).
- The third step is the absorption of nitrogen dioxide in water to form nitric acid.
2. Catalyst requirements:
- The catalyst used in the ammonia oxidation process must have several key properties.
- It should promote the desired reaction while minimizing the formation of unwanted byproducts.
- It should have high activity and selectivity towards the desired reaction.
- It should be stable under the reaction conditions and resist deactivation.
3. Platinum-Rhodium gauze catalyst:
- The Platinum-Rhodium gauze is widely used as the catalyst in the Ostwald process.
- It is a mesh-like structure made of platinum and rhodium metals.
- The catalyst is typically supported on a ceramic or metal substrate.
- The Platinum-Rhodium gauze catalyst has several advantages for this reaction.
4. Advantages of Platinum-Rhodium gauze catalyst:
- High activity: Platinum and rhodium have high catalytic activity for the oxidation of ammonia.
- Selectivity: The catalyst promotes the desired oxidation reactions while minimizing side reactions.
- Resistance to deactivation: The Platinum-Rhodium gauze catalyst is stable under the reaction conditions and does not easily get deactivated.
- Surface area: The mesh-like structure of the catalyst provides a large surface area for the reactants to come into contact with the catalyst, enhancing the reaction rate.
In conclusion, the Platinum-Rhodium gauze catalyst is used for the oxidation of ammonia to produce nitric acid in the Ostwald process due to its high activity, selectivity, stability, and large surface area.