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Compound A is converted to B on reaction with CHCl3 and KOH. The compound B is toxic and can be decomposed by C.
A, B and C respectively are:
  • a)
    Secondary amine, nitrile compound, conc. NaOH
  • b)
    Primary amine, isonitrile compound, conc. HCl
  • c)
    Secondary amine, isonitrile compound, conc. NaOH
  • d)
    Primary amine, nitrile compound, conc. HCl
Correct answer is option 'B'. Can you explain this answer?
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Compound A is converted to B on reaction with CHCl3 and KOH. The compo...
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Compound A is converted to B on reaction with CHCl3 and KOH. The compo...
Explanation:
When Compound A reacts with CHCl3 (chloroform) and KOH (potassium hydroxide), it undergoes a reaction called the Carbylamine Reaction. This reaction is used to distinguish between primary, secondary, and tertiary amines.

Carbylamine Reaction:
In the Carbylamine Reaction, an amine reacts with chloroform (CHCl3) and KOH to form an isocyanide or isonitrile compound. This reaction is specific to primary amines and does not occur with secondary or tertiary amines.

Reaction:
The reaction can be represented as follows:

R-NH2 + CHCl3 + KOH → R-N=C (isocyanide) + 3H2O

Interpretation:
Compound A is converted to compound B, which is toxic. This indicates that Compound A is a primary amine. Compound B is formed as a result of the Carbylamine Reaction, which confirms that Compound A is a primary amine.

Decomposition:
Compound B can be decomposed by concentrated hydrochloric acid (conc. HCl). The isocyanide group (-N=C) in Compound B is unstable and can be easily hydrolyzed by strong acids such as conc. HCl to form a primary amine and carbon dioxide.

Decomposition Reaction:
The decomposition of Compound B can be represented as follows:

R-N=C + 2HCl → R-NH2 (primary amine) + CO2↑ + H2O

Conclusion:
Based on the information provided, Compound A is a primary amine and Compound B is an isocyanide compound. The decomposition of Compound B can be achieved by using concentrated hydrochloric acid. Therefore, the correct answer is option 'B' - Primary amine, isocyanide compound, and conc. HCl.
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Compound A is converted to B on reaction with CHCl3 and KOH. The compound B is toxic and can be decomposed by C.A, B and C respectively are:a)Secondary amine, nitrile compound, conc. NaOHb)Primary amine, isonitrile compound, conc. HClc)Secondary amine, isonitrile compound, conc. NaOHd)Primary amine, nitrile compound, conc. HClCorrect answer is option 'B'. Can you explain this answer?
Question Description
Compound A is converted to B on reaction with CHCl3 and KOH. The compound B is toxic and can be decomposed by C.A, B and C respectively are:a)Secondary amine, nitrile compound, conc. NaOHb)Primary amine, isonitrile compound, conc. HClc)Secondary amine, isonitrile compound, conc. NaOHd)Primary amine, nitrile compound, conc. HClCorrect answer is option 'B'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Compound A is converted to B on reaction with CHCl3 and KOH. The compound B is toxic and can be decomposed by C.A, B and C respectively are:a)Secondary amine, nitrile compound, conc. NaOHb)Primary amine, isonitrile compound, conc. HClc)Secondary amine, isonitrile compound, conc. NaOHd)Primary amine, nitrile compound, conc. HClCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Compound A is converted to B on reaction with CHCl3 and KOH. The compound B is toxic and can be decomposed by C.A, B and C respectively are:a)Secondary amine, nitrile compound, conc. NaOHb)Primary amine, isonitrile compound, conc. HClc)Secondary amine, isonitrile compound, conc. NaOHd)Primary amine, nitrile compound, conc. HClCorrect answer is option 'B'. Can you explain this answer?.
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