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Determining Lewis dot structures can be used to determine whether a compound has any bond dipoles and consequently any molecular dipole. Which of the following compounds does NOT have a molecular dipole?
  • a)
    NH3
  • b)
    PO33-
  • c)
    CIO3-
  • d)
    SO3
Correct answer is option 'D'. Can you explain this answer?
Most Upvoted Answer
Determining Lewis dot structures can be used to determine whether a co...

Explanation:

NH3:
- NH3, or ammonia, has a molecular dipole because the nitrogen atom is more electronegative than the hydrogen atoms. This results in a partial negative charge on the nitrogen atom and partial positive charges on the hydrogen atoms.

PO33-:
- PO33- does have a molecular dipole. The molecule has a trigonal pyramidal shape with a lone pair on the central phosphorus atom. This lone pair causes the molecule to have a net dipole moment.

ClO3-:
- ClO3- also has a molecular dipole. The molecule has a trigonal planar shape with one of the oxygen atoms having a double bond with the central chlorine atom. This unequal distribution of electrons results in a net dipole moment.

SO3:
- SO3 does not have a molecular dipole. The molecule has a trigonal planar shape with all sulfur-oxygen bonds being identical. The electronegativities of sulfur and oxygen are similar, leading to a symmetrical distribution of electrons and no net dipole moment.

Therefore, the compound that does NOT have a molecular dipole is SO3.
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Determining Lewis dot structures can be used to determine whether a co...
The hypochlorite ion ClO3has 2 double-bonded oxygens and 1 single-bonded oxygen to the chlorine central atom. Since chlorine can have 7 bonds, with 5 bonds to oxygen, there are 2 electrons remaining as an unbonded pair. Hypochlorite has the trigonal pyramidal molecular geometry.
The phosphite ion PO33- has a central phosphorus atom with 3 single-bonded oxygens each with a negative charge. Since phosphorus has 5 valence electrons, there are 2 electrons remaining for a lone pair. Phosphite has the trigonal pyramidal molecular geometry.
Ammonia NH3 , has a central nitrogen with 3 single-bonded hydrogens. Since nitrogen has 5 valence electrons, there are 2 electrons remaining for an unbonded pair.
Sulfur trioxide SO3 has a central sulfur atom attached to 3 oxygens with double bonds. The molecular geometry is trigonal planar, and it has no molecular dipole.
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