One method for sterilizing the surface of an article contaminated with...
Molecular Geometry of Chlorine Trifluoride
Chlorine trifluoride (ClF3) exhibits a unique molecular geometry due to the presence of lone pairs on the chlorine atom.
Valence Shell Electron Pair Repulsion (VSEPR) Theory
- According to VSEPR theory, the shape of a molecule is determined by the repulsion between electron pairs around a central atom.
- Chlorine has 7 valence electrons and forms three single bonds with fluorine atoms, using up 3 of its electrons.
- This leaves 4 electrons, which exist as 2 lone pairs.
Shape Determination
- The presence of these lone pairs affects the geometry:
- The three bonding pairs (Cl-F) arrange themselves to minimize repulsion, forming an equatorial plane.
- The two lone pairs occupy axial positions, leading to a distortion in the shape.
T-Shaped Geometry
- As a result, the molecular geometry of ClF3 can be classified as T-shaped:
- The three fluorine atoms occupy the corners of a “T,” while the lone pairs are positioned above and below the plane.
Comparison with Other Geometries
- This is distinct from:
- Trigonal planar (no lone pairs, 3 bonding pairs)
- Trigonal pyramidal (4 electron pairs, 3 bonding and 1 lone pair)
- Trigonal bipyramidal (5 electron pairs, 5 bonding pairs)
Conclusion
- Therefore, the correct answer for the molecular geometry of chlorine trifluoride is T-shaped, making option 'C' accurate.
One method for sterilizing the surface of an article contaminated with...
Chlorine has seven valence electrons and can expand its octet to form 7 bonds. Chlorine has to be the central atom.
Fluorine has to be single bonded since it cannot expand its octet. Chlorine has 3 single bonds to fluorine, and there are 4 electrons left to make 2 lone pairs.
Count the number of attaching atoms and lone pairs to determine the electronic geometry. For a count of 5, the geometry is trigonal bipyramidal.
The molecular geometries for trigonal bipyramidal electronic geometry are linear, T-shaped, see-saw, and trigonal bipyramidal.
With 3 attached atoms, the molecular geometry is T-shaped. Here is the Lewis dot structure: