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Fe3+ cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solution due to the formation of:
- a)[Fe(H2O)6]2[Fe(CN)6]
- b)Fe2[Fe(CN)6]2
- c)Fe3[Fe(OH)2(CN)4]2
- d)Fe4[Fe(CN)6]3
Correct answer is option 'D'. Can you explain this answer?
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Fe3+cation gives a Prussian blue precipitate on addition of potassium ...
Formation of Prussian Blue
Prussian blue is a deep blue pigment formed when iron(III) ions (Fe3+) react with ferrocyanide ions (Fe(CN)6)4-. This reaction is significant in inorganic chemistry and is used as a qualitative test for Fe3+ ions.
Reaction Overview
- When potassium ferrocyanide (K4[Fe(CN)6]) is added to a solution containing Fe3+, it leads to the formation of a complex.
- The reaction can be represented as follows:
Fe3+ + [Fe(CN)6]4- → Prussian blue precipitate.
Correct Compound Formation
- The correct compound formed in this reaction is Fe4[Fe(CN)6]3. This is represented as:
- Fe4[Fe(CN)6]3 is a complex where four Fe3+ ions coordinate with three [Fe(CN)6]4- ions.
- This stoichiometry ensures that the charges balance out, resulting in an insoluble blue precipitate.
Other Options Explained
- Option A: [Fe(H2O)6]2[Fe(CN)6] - This represents a different complex and does not correspond to the formation of Prussian blue.
- Option B: Fe2[Fe(CN)6]2 - Here, the stoichiometry does not support the formation of Prussian blue.
- Option C: Fe3[Fe(OH)2(CN)4]2 - This involves hydroxide ions and does not form Prussian blue.
Conclusion
- The formation of Prussian blue is a classic example of a coordination complex, demonstrating the interaction of transition metals with ligands, specifically ferrocyanide ions.
- Thus, the correct answer to the question is indeed option D: Fe4[Fe(CN)6]3.
Prussian blue is a deep blue pigment formed when iron(III) ions (Fe3+) react with ferrocyanide ions (Fe(CN)6)4-. This reaction is significant in inorganic chemistry and is used as a qualitative test for Fe3+ ions.
Reaction Overview
- When potassium ferrocyanide (K4[Fe(CN)6]) is added to a solution containing Fe3+, it leads to the formation of a complex.
- The reaction can be represented as follows:
Fe3+ + [Fe(CN)6]4- → Prussian blue precipitate.
Correct Compound Formation
- The correct compound formed in this reaction is Fe4[Fe(CN)6]3. This is represented as:
- Fe4[Fe(CN)6]3 is a complex where four Fe3+ ions coordinate with three [Fe(CN)6]4- ions.
- This stoichiometry ensures that the charges balance out, resulting in an insoluble blue precipitate.
Other Options Explained
- Option A: [Fe(H2O)6]2[Fe(CN)6] - This represents a different complex and does not correspond to the formation of Prussian blue.
- Option B: Fe2[Fe(CN)6]2 - Here, the stoichiometry does not support the formation of Prussian blue.
- Option C: Fe3[Fe(OH)2(CN)4]2 - This involves hydroxide ions and does not form Prussian blue.
Conclusion
- The formation of Prussian blue is a classic example of a coordination complex, demonstrating the interaction of transition metals with ligands, specifically ferrocyanide ions.
- Thus, the correct answer to the question is indeed option D: Fe4[Fe(CN)6]3.
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Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer?
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Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer?.
Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer?.
Solutions for Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer? in English & in Hindi are available as part of our courses for JEE.
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Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer?, a detailed solution for Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer? has been provided alongside types of Fe3+cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solutiondue to the formation of:a)[Fe(H2O)6]2[Fe(CN)6]b)Fe2[Fe(CN)6]2c)Fe3[Fe(OH)2(CN)4]2d)Fe4[Fe(CN)6]3Correct answer is option 'D'. Can you explain this answer? theory, EduRev gives you an
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