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Addition of two electrons to the bismuth cluster  Bi3+5 results in a change of structure type from
  • a)
    closo to nido
  • b)
    nido to arachno
  • c)
    closo to arachno
  • d)
    arachno to hypho 
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Addition of two electrons to the bismuth clusterBi3+5 results in a cha...
  • Total number of valence electrons for Bi3+
    = 5 × 5 - 3
    = 22
  • Hence, it follows the (4n + 2) rule, for n = 5
  • Thus, Bi3+has a close structure.
  • On addition of 2 electrons, the total number of valence electrons for it become
    ​= 22 + 2
    = 24
  • Hence, now it follows the (4n + 4) rule, for n = 5 
  • The geometry will be Nido/
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