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The number of inorganic sulfides in cubane like ferredoxin and their removal method, respectively, are
  • a)
    eight and washing with an acid
  • b)
    four and washing with a base
  • c)
    eight and washing with a base
  • d)
    four and washing with an acid
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
The number of inorganic sulfides in cubane like ferredoxin and their r...
  • Inorganic sulfides can be present in cubane-like ferredoxins, which are metalloproteins involved in electron transfer reactions. The number of inorganic sulfides in cubane-like ferredoxins can vary depending on the specific ferredoxin and its metal center.
  • Typically, cubane-like ferredoxins contain a cubane cluster of iron-sulfur (Fe-S) atoms, which can include both inorganic sulfides (S2-) and inorganic iron (Fe2+). The cluster is often represented as [4Fe-4S] or [Fe4S4], indicating the presence of four iron atoms and four sulfur atoms in the cluster.
  • Cubane like ferredoxin is Fe4S4
  • It has four inorganic sulfide (S2-) which can be removed by treatment with acid.
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Most Upvoted Answer
The number of inorganic sulfides in cubane like ferredoxin and their r...
The correct answer is option 'D': four inorganic sulfides and washing with an acid.

Explanation:
Cubane is a hydrocarbon molecule with eight carbon atoms arranged at the corners of a cube, and it is often used as a structural motif in inorganic chemistry. Ferredoxin is a type of protein that contains cubane-like clusters of iron and sulfur atoms.

1. Inorganic sulfides in cubane-like ferredoxin:
Inorganic sulfides are sulfur atoms that are bonded to inorganic elements, such as metals. In cubane-like ferredoxin, there are four inorganic sulfides present. These sulfides are coordinated with iron atoms in the cubane cluster.

2. Removal method:
The removal of inorganic sulfides from cubane-like ferredoxin can be achieved by washing with an acid. Acidic conditions can facilitate the dissociation of the inorganic sulfide bonds with the iron atoms, leading to their removal from the protein.

3. Acidic washing:
The acidic washing involves treating the cubane-like ferredoxin with an acid solution. The acid can protonate the sulfide ions, making them more susceptible to dissociation from the iron atoms. This process can be done by adjusting the pH of the solution to an acidic range, typically below pH 7.

4. Acid-base reactions:
The acid-base reactions that occur during the acidic washing can be represented by the following equations:
- Acid (H+) + Sulfide (S2-) → Hydrogen sulfide (H2S)
- Iron-sulfide bond (Fe-S) + Acid (H+) → Iron ion (Fe2+) + Hydrogen sulfide (H2S)

5. Acid washing vs. base washing:
While both acid and base washing can be used to remove inorganic sulfides, the choice of the washing method depends on the specific system and the desired outcome. In this case, acid washing is the appropriate method because it is more effective at dissociating the inorganic sulfides from the cubane-like ferredoxin.

In conclusion, the number of inorganic sulfides in cubane-like ferredoxin is four, and the appropriate method for their removal is washing with an acid.
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The number of inorganic sulfides in cubane like ferredoxin and their removal method, respectively, area)eight and washing with an acidb)four and washing with a basec)eight and washing with a based)four and washing with an acidCorrect answer is option 'D'. Can you explain this answer?
Question Description
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