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Observe the underlined/bold hydrogen. In HNMR, how many spectral lines will that bolded hydrogen be split into?
  • a)
    0 lines
  • b)
    9 lines (multiplet)
  • c)
    3 lines (triplet)
  • d)
    10 lines (multiplet)
Correct answer is option 'D'. Can you explain this answer?
Most Upvoted Answer
Observe the underlined/bold hydrogen. In HNMR, how many spectral lines...
(9+1)=10 lines
  • Within 1H NMR spectroscopy there are a couple important factors to understand, including the ppm shift (Delta) and the splitting pattern. Here we are focusing on the splitting pattern for individual hydrogens. This is important for it lays the groundwork for understanding the patterns of peaks seen on large compound NMR’s. 
  • When determining the splitting of any hydrogen you must use the n+1 rule. Before going into that rule we must understand two things, 1. only nonequivalent hydrogens (protons) couple and 2. usually they only couple to other hydrogens (protons) attached to adjacent carbons. Nonequivalent means the protons occupy their own unique spatial environment with different atoms surrounding them.
  • Typically two hydrogens attached to the same carbon are equivalent (though this isn’t always the case and you must think about where the hydrogens are located in space and see whether they are adjacent to different or similar chemical groups). 
  • The n+1 rule is performed as follows. N stands for the number of equivalent protons that are not equivalent to the proton of interest (the one we are trying to determine the splitting for). We multiply together each group of protons that are nonequivalent to the proton of interest. For example, lets say there are two groups of protons that are nonequivalent to the proton of interest, in group A there are 2 protons, and in group B there are 3 protons.
  • We would use the n+1 rule for group A and get (2+1) = 3 and for group B get (3+1) = 4. We would then multiply these two numbers together to get the splitting for the proton of interest, thus 3 x 4 = 12 lines that the proton of interest would be split into. Proper use of this rule should allow you to get all NMR splitting questions correct (and elevate your understanding of why a certain NMR printout looks the way it does). 
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Observe the underlined/bold hydrogen. In HNMR, how many spectral lines will that bolded hydrogen be split into?a)0linesb)9lines (multiplet)c)3lines (triplet)d)10lines (multiplet)Correct answer is option 'D'. Can you explain this answer?
Question Description
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