JEE Exam > JEE Questions > The Arrhenius parameters for the thermal deco...
Start Learning for Free
The Arrhenius parameters for the thermal decomposition of NOCl represented by
2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculate
the entropy, enthalpy and free energy of activation for the reaction at 300 K.
?
2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculate
the entropy, enthalpy and free energy of activation for the reaction at 300 K.
?
Most Upvoted Answer
The Arrhenius parameters for the thermal decomposition of NOCl represe...
- Entropy Calculation:
- Enthalpy Calculation:
- Free Energy of Activation Calculation:
Entropy Calculation:
The entropy of activation (ΔS‡) can be calculated using the Arrhenius equation:
ΔS‡ = -R * ln(A)
where R is the gas constant (8.314 J/mol∙K) and A is the pre-exponential factor (1 x 10^13 M^-1s^-1).
Plugging in the values, we get:
ΔS‡ = -8.314 * ln(1 x 10^13)
ΔS‡ ≈ -8.314 * 23.03
ΔS‡ ≈ -191.48 J/mol∙K
Enthalpy Calculation:
The enthalpy of activation (ΔH‡) can be calculated using the Arrhenius equation:
ΔH‡ = Ea + RT
where Ea is the activation energy (104 kJ/mol), R is the gas constant (8.314 J/mol∙K), and T is the temperature (300 K).
Plugging in the values, we get:
ΔH‡ = 104 + 8.314 * 300
ΔH‡ ≈ 104 + 2494.2
ΔH‡ ≈ 2598.2 kJ/mol
Free Energy of Activation Calculation:
The free energy of activation (ΔG‡) can be calculated using the equation:
ΔG‡ = ΔH‡ - TΔS‡
Plugging in the values we calculated earlier, we get:
ΔG‡ = 2598.2 - 300 * (-191.48)
ΔG‡ ≈ 2598.2 + 57444
ΔG‡ ≈ 60042.2 kJ/mol
Therefore, at 300 K, the entropy of activation is approximately -191.48 J/mol∙K, the enthalpy of activation is approximately 2598.2 kJ/mol, and the free energy of activation is approximately 60042.2 kJ/mol for the thermal decomposition of NOCl.
- Enthalpy Calculation:
- Free Energy of Activation Calculation:
Entropy Calculation:
The entropy of activation (ΔS‡) can be calculated using the Arrhenius equation:
ΔS‡ = -R * ln(A)
where R is the gas constant (8.314 J/mol∙K) and A is the pre-exponential factor (1 x 10^13 M^-1s^-1).
Plugging in the values, we get:
ΔS‡ = -8.314 * ln(1 x 10^13)
ΔS‡ ≈ -8.314 * 23.03
ΔS‡ ≈ -191.48 J/mol∙K
Enthalpy Calculation:
The enthalpy of activation (ΔH‡) can be calculated using the Arrhenius equation:
ΔH‡ = Ea + RT
where Ea is the activation energy (104 kJ/mol), R is the gas constant (8.314 J/mol∙K), and T is the temperature (300 K).
Plugging in the values, we get:
ΔH‡ = 104 + 8.314 * 300
ΔH‡ ≈ 104 + 2494.2
ΔH‡ ≈ 2598.2 kJ/mol
Free Energy of Activation Calculation:
The free energy of activation (ΔG‡) can be calculated using the equation:
ΔG‡ = ΔH‡ - TΔS‡
Plugging in the values we calculated earlier, we get:
ΔG‡ = 2598.2 - 300 * (-191.48)
ΔG‡ ≈ 2598.2 + 57444
ΔG‡ ≈ 60042.2 kJ/mol
Therefore, at 300 K, the entropy of activation is approximately -191.48 J/mol∙K, the enthalpy of activation is approximately 2598.2 kJ/mol, and the free energy of activation is approximately 60042.2 kJ/mol for the thermal decomposition of NOCl.
Attention JEE Students!
To make sure you are not studying endlessly, EduRev has designed JEE study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in JEE.
|
Explore Courses for JEE exam
|
|
Similar JEE Doubts
Top Courses for JEEView all
The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.?
Question Description
The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.?.
The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.?.
Solutions for The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? in English & in Hindi are available as part of our courses for JEE.
Download more important topics, notes, lectures and mock test series for JEE Exam by signing up for free.
Here you can find the meaning of The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? defined & explained in the simplest way possible. Besides giving the explanation of
The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.?, a detailed solution for The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? has been provided alongside types of The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? theory, EduRev gives you an
ample number of questions to practice The Arrhenius parameters for the thermal decomposition of NOCl represented by2NOCl ሺgሻ → 2NOሺgሻ Clଶሺgሻ are A = 1 x 1013 M-1s-1 and Ea = 104 kJ/mol. Calculatethe entropy, enthalpy and free energy of activation for the reaction at 300 K.? tests, examples and also practice JEE tests.
|
|
Explore Courses for JEE exam
|
|
Suggested Free Tests
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
|
© EduRev
|
Education Revolution
|
Follow Us
|
Signup to see your scores
go up within 7 days!
Access 1000+ FREE Docs, Videos and Tests
Takes less than 10 seconds to signup