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A rigid insulated tank has two equal parts by partition. First part initially contains 5k mol of an ideal gas at
500 kPa, 400C and other part is evacuated. If partition is removed, then the gas fills the entire tank, what will be the total entropy change during this process.
  • a)
    28.81 kJ/K
  • b)
    14.4 kJ/K
  • c)
    7.2 kJ/K
  • d)
    21.6 kJ/K
Correct answer is option 'A'. Can you explain this answer?
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A rigid insulated tank has two equal parts by partition. First part in...
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Solution:

Given data:

Number of moles in the first part of the tank, n1 = 5 kmol

Pressure, P1 = 500 kPa

Temperature, T1 = 400°C = 673.15 K

Volume of each part of the tank, V = V1 + V2

Total number of moles in the tank after removal of the partition = n1 + n2

As the gas is assumed to be ideal, we can use the ideal gas equation to calculate the volume of the gas in the first part of the tank.

PV = nRT

V1 = n1RT1 / P1

V1 = 5 × 8.314 × 673.15 / 500

V1 = 5.629 m³

As both parts of the tank are equal in volume, V2 = V1 = 5.629 m³

The total volume of the tank after removal of the partition is V = 2V1 = 2V2 = 11.258 m³

The final pressure and temperature of the gas in the tank can be calculated using the ideal gas equation and the conservation of mass.

n1RT1 / V1 = (n1 + n2)RT2 / V

T2 = (n1 + n2)T1 / n1

T2 = (5 + n2 / 5) × 673.15 / 5

T2 = (n2 / 5) × 134.63 + 673.15

P2 = nRT / V

P2 = (n1 + n2)RT2 / V

P2 = (5 + n2 / 5) × 8.314 × [(n2 / 5) × 134.63 + 673.15] / 5.629

P2 = (n2 / 5) × 327.7 + 206.3 kPa

The change in entropy of the gas can be calculated using the ideal gas equation and the definition of entropy.

ΔS = ∫(dQ / T)

For an ideal gas, dQ = nCv dT

ΔS = nCv ln(T2 / T1)

Cv for a diatomic gas = 5R / 2

ΔS = (5 + n2 / 5) × (5R / 2) ln[(n2 / 5) × 134.63 + 673.15 / 673.15]

ΔS = (5 + n2 / 5) × (5R / 2) ln(n2 / 5 + 1.013)

As the total number of moles in the tank after removal of the partition is not known, we can assume a small change in the number of moles, dn2, and calculate the corresponding change in entropy, dS.

dS = (5 + (n2 + dn2) / 5) × (5R / 2) ln[(n2 + dn2) / 5 + 1.013] - (5 + n2 / 5) × (5R / 2) ln(n2 / 5 + 1.013)

dS = (5R / 2) ln[(n2 + dn2) / n
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