Generally, the first ionization energy increases along a period. But t...
Explanation:
First ionization energy is the energy required to remove one electron from the outermost shell of an atom in the gaseous phase. In general, the first ionization energy increases along a period due to the following factors:
1. Increasing nuclear charge: As we move across a period, the number of protons in the nucleus increases, leading to a stronger attractive force between the nucleus and the electrons. This increased attraction makes it more difficult to remove an electron, thus increasing the ionization energy.
2. Decreasing atomic radius: As we move across a period, the atomic radius decreases due to the increasing nuclear charge and the addition of electrons to the same energy level. The closer the outermost electron is to the nucleus, the stronger the attraction, and the higher the ionization energy.
However, there are a few exceptions to this trend. For example, in the case of Na and Mg, the first ionization energy of Na (496 kJ/mol) is lower than that of Mg (738 kJ/mol), despite Na being located to the left of Mg in the periodic table.
Reasoning:
The reason for this exception lies in the electronic configurations of Na and Mg. Na has a configuration of 1s²2s²2p⁶3s¹, while Mg has a configuration of 1s²2s²2p⁶3s². In the case of Na, the electron being removed is from the 3s orbital, which is further away from the nucleus compared to the 3s² orbital of Mg. The 3s electron in Na experiences less shielding from the inner electrons, leading to a weaker attraction to the nucleus and a lower ionization energy.
Conclusion:
Therefore, when comparing Na and Mg, Na has a lower first ionization energy due to the electron being removed from a higher energy level and experiencing less nuclear attraction. Hence, option 'A' is the correct answer.
Generally, the first ionization energy increases along a period. But t...
In other 3 options I.e. b, c & d. the first element have a full filled or half filled shell and this gives them extra stability than the other element in the same option, thus they have a higher ionisation energy but in option a, the size decreases and outer shell is also fulfilled so its ionisation energy increases. so it's ionisation energy increases