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Reactive intermediate formed in the following reaction is:
  • a)
    Carbene
  • b)
    Isocyanate
  • c)
    Nitrene
  • d)
    Carbanion 
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Reactive intermediate formed in the following reaction is:a)Carbeneb)I...
The reaction of bromine with sodium hydroxide forms sodium hypobromite in situ, which transforms the primary amide into an intermediate isocyanate. The formation of an intermediate nitrene is not possible because it also implies the formation of a hydroxamic acid as a byproduct, which has never been observed. The intermediate isocyanate is hydrolyzed to a primary amine, giving off carbon dioxide.
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Most Upvoted Answer
Reactive intermediate formed in the following reaction is:a)Carbeneb)I...
Option C is equally correct since the isocyanate is formed by a Wolff rearrangement-type reaction of the nitrene.
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Community Answer
Reactive intermediate formed in the following reaction is:a)Carbeneb)I...
The reaction of bromine with sodium hydroxide forms sodium hypobromite in situ, which transforms the primary amide into an intermediate isocyanate. The formation of an intermediate nitrene is not possible because it also implies the formation of a hydroxamic acid as a byproduct, which has never been observed. The intermediate isocyanate is hydrolyzed to a primary amine, giving off carbon dioxide.
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Reactive intermediate formed in the following reaction is:a)Carbeneb)Isocyanatec)Nitrened)CarbanionCorrect answer is option 'B'. Can you explain this answer?
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