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Which of the following is not a π bonded complex?
  • a)
    Zeise's salt
  • b)
    Ferrocene
  • c)
    Dibenzene chromium
  • d)
    Tetraethyl lead
Correct answer is option 'D'. Can you explain this answer?
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Which of the following is not a π bonded complex?a)Zeise's saltb)Ferro...
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Which of the following is not a π bonded complex?a)Zeise's saltb)Ferro...
Introduction:
In coordination chemistry, π-bonded complexes are those in which the metal atom forms π-bonds with ligands. These complexes are characterized by the presence of metal-ligand π-bonds, which involve the donation of electron density from filled π-orbitals of the ligands to empty or partially filled d-orbitals of the metal. Let's analyze the given options to determine which one is not a π-bonded complex.

Analysis:
a) Zeise's salt: Zeise's salt, also known as potassium trichloro(ethylene)platinate(II), is a π-bonded complex. It consists of a central platinum atom bonded to three chloride ligands and one ethylene ligand through π-bonds. Therefore, option (a) is a π-bonded complex.

b) Ferrocene: Ferrocene is an organometallic compound in which an iron atom is sandwiched between two cyclopentadienyl rings. The iron atom forms π-bonds with both cyclopentadienyl rings, making it a π-bonded complex. Therefore, option (b) is a π-bonded complex.

c) Dibenzene chromium: Dibenzene chromium, also known as bis(benzene)chromium, is a compound in which a chromium atom is coordinated to two benzene ligands. The coordination between the chromium atom and the benzene ligands involves π-bonding. Therefore, option (c) is a π-bonded complex.

d) Tetraethyl lead: Tetraethyl lead is an organometallic compound in which a lead atom is bonded to four ethyl groups. The bonding between the lead atom and the ethyl groups does not involve π-bonding. Instead, it is primarily a result of σ-bonding. Therefore, option (d) is not a π-bonded complex.

Conclusion:
Among the given options, tetraethyl lead (option d) is not a π-bonded complex. It does not involve the formation of π-bonds between the lead atom and the ethyl groups. The other options, Zeise's salt, ferrocene, and dibenzene chromium, are all examples of π-bonded complexes.
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Which of the following is not a π bonded complex?a)Zeise's saltb)Ferrocenec)Dibenzene chromiumd)Tetraethyl leadCorrect answer is option 'D'. Can you explain this answer?
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Which of the following is not a π bonded complex?a)Zeise's saltb)Ferrocenec)Dibenzene chromiumd)Tetraethyl leadCorrect answer is option 'D'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Which of the following is not a π bonded complex?a)Zeise's saltb)Ferrocenec)Dibenzene chromiumd)Tetraethyl leadCorrect answer is option 'D'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following is not a π bonded complex?a)Zeise's saltb)Ferrocenec)Dibenzene chromiumd)Tetraethyl leadCorrect answer is option 'D'. Can you explain this answer?.
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