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Which of the following statements is(are) true for [Cu(NO2)6]4– and [Fe(H2O)6]3+ ?
  • a)
    Both are outer orbital complexes.
  • b)
    Both are inner orbital complexes with magnetic moment equal to 1.73 B.M.
  • c)
    The former complex is paramagnetic with one unpaired electron while later one is paramagnetic with five unpaired electrons.
  • d)
    The former is outer orbital complex and later is inner orbital complexes respectively.
Correct answer is option 'A,C'. Can you explain this answer?
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Which of the following statements is(are) true for [Cu(NO2)6]4– ...
1. The coordination number of copper in [Cu(NO2)6]4- is 6. True.
2. The complex ion has a square planar geometry. False. The complex ion [Cu(NO2)6]4- has an octahedral geometry.
3. The complex ion has a total charge of -4. True. The subscript 4- indicates the total charge of the complex ion.
4. The complex ion contains 6 nitrite ligands bonded to the copper ion. True. The formula [Cu(NO2)6]4- indicates that there are 6 nitrite ligands bonded to the copper ion.
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Crystal field theory views the bonding in complexes as arising from electrostatic interaction and considers the effect of the ligand charges on the energies of the metal ion d-orbitals.In this theory, a ligand lone pair is modelled as a point negative charge that repels electrons in the d-orbitals of the central metal ion. The theory concentrated on the resulting splitting of the d-orbitals in two groups with different energies and used that splitting to rationalize and correlate the optical spectra, thermodynamic stability, and magnetic properties of complexes. This energy splitting between the two sets of dorbitals is called the crystal field splitting D.In general, the crystal field splitting energy D corresponds to wavelength of light in visible region of the spectrum, and colours of the complexes can therefore be attributed to electronic transition between the lower-and higher energy sets of d-orbitals.In general, the colour that the we see is complementry to the colour absorbed.Different metal ion have different values of D, which explains why their complexes with the same ligand have different colour.Similarly, the crystal field splitting also depends on the nature of ligands and as the ligand for the same metal varies from H2O to NH3 to ethylenediamine, D for complexes increases. Accordingly, the electronic transition shifts to higher energy (shorter wavelength) as the ligand varies from H2O to NH3 to en, thus accounting for the variation in colour.Crystal field theory accounts for the magnetic properties of complexes in terms of the relative values of and the spin pairing energy P. Small values favour high spin complexes, and large Dvalues favour low spin complexes.Which of the following statements is incorrect?

Which of the following statements is(are) true for [Cu(NO2)6]4– and [Fe(H2O)6]3+ ?a)Both are outer orbital complexes.b)Both are inner orbital complexes with magnetic moment equal to 1.73 B.M.c)The former complex is paramagnetic with one unpaired electron while later one is paramagnetic with five unpaired electrons.d)The former is outer orbital complex and later is inner orbital complexes respectively.Correct answer is option 'A,C'. Can you explain this answer?
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Which of the following statements is(are) true for [Cu(NO2)6]4– and [Fe(H2O)6]3+ ?a)Both are outer orbital complexes.b)Both are inner orbital complexes with magnetic moment equal to 1.73 B.M.c)The former complex is paramagnetic with one unpaired electron while later one is paramagnetic with five unpaired electrons.d)The former is outer orbital complex and later is inner orbital complexes respectively.Correct answer is option 'A,C'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Which of the following statements is(are) true for [Cu(NO2)6]4– and [Fe(H2O)6]3+ ?a)Both are outer orbital complexes.b)Both are inner orbital complexes with magnetic moment equal to 1.73 B.M.c)The former complex is paramagnetic with one unpaired electron while later one is paramagnetic with five unpaired electrons.d)The former is outer orbital complex and later is inner orbital complexes respectively.Correct answer is option 'A,C'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following statements is(are) true for [Cu(NO2)6]4– and [Fe(H2O)6]3+ ?a)Both are outer orbital complexes.b)Both are inner orbital complexes with magnetic moment equal to 1.73 B.M.c)The former complex is paramagnetic with one unpaired electron while later one is paramagnetic with five unpaired electrons.d)The former is outer orbital complex and later is inner orbital complexes respectively.Correct answer is option 'A,C'. Can you explain this answer?.
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