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Calculate the pressure exerted by one mole of CO2 gas at 273 K, if the van der Waals’ constant ‘a’ = 3.592 dm6 atm mol–2. Assume that the volume occupied by CO2 molecules is negligible.
    Correct answer is '34.98'. Can you explain this answer?
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    Calculate the pressure exerted by one mole of CO2 gas at 273 K, if the...
    Ans.
    According to Van Der waal’s equation
    (for 1 mole of the gas)
    Since,the volume occupied by CO2 molecules is negligible, therefore, b =o
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    Calculate the pressure exerted by one mole of CO2 gas at 273 K, if the...
    Equation of state is used with the following values for CO2: a = 3.592 L^2 atm/mol^2 and b = 0.0427 L/mol.

    The van der Waals equation of state is:

    (P + a(n/V)^2)(V - nb) = nRT

    where P is the pressure, V is the volume, n is the number of moles, R is the gas constant (0.08206 L atm/mol K), T is the temperature in Kelvin, a is the attractive force constant, and b is the volume of the molecules.

    We are given that we have one mole of CO2 gas at 273 K. We can assume that the volume is 1 L since we have one mole. Therefore, we can rewrite the equation as:

    (P + a/V^2)(V - b) = RT

    Substituting in the values given for CO2, we get:

    (P + (3.592 L^2 atm/mol^2)/(1 L)^2)(1 L - 0.0427 L) = (1 mol)(0.08206 L atm/mol K)(273 K)

    Simplifying:

    (P + 14.384 atm)(0.9573 L) = 22.414 L atm/mol

    P + 13.783 atm = 23.357 atm

    P = 9.574 atm

    Therefore, the pressure exerted by one mole of CO2 gas at 273 K using the van der Waals equation of state is 9.574 atm.
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