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Ethyl alcohol on oxidation with K₂Cr₂O₇ gives
  • a)
    Acetic acid
  • b)
    Acetaldehyde
  • c)
    Formaldehyde
  • d)
    Formic acid
Correct answer is option 'A'. Can you explain this answer?
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Ethyl alcohol on oxidation with K₂Cr₂O₇ givesa) ...
Oxidation of Ethyl Alcohol with KCrO4 to form Acetic Acid

Oxidation of Ethyl Alcohol with Potassium Dichromate (K2Cr2O7) is a redox reaction. In this reaction, ethyl alcohol is oxidized to acetic acid by the strong oxidizing agent potassium dichromate. The process of oxidizing alcohol is a common reaction in organic chemistry.

The balanced chemical equation for the reaction is given as follows:

3 CH3CH2OH + 2 K2Cr2O7 + 8 H2SO4 → 3 CH3COOH + 2 Cr2(SO4)3 + 2 K2SO4 + 11 H2O

Explanation of the reaction:

- In the reaction, potassium dichromate acts as a strong oxidizing agent.
- Ethyl alcohol is a primary alcohol and it can be converted to an aldehyde or a carboxylic acid by oxidation.
- However, in the presence of strong oxidizing agents like potassium dichromate, the oxidation of alcohol goes all the way to the carboxylic acid stage.
- The oxidation is carried out in the presence of sulfuric acid, which acts as a catalyst.
- The reaction is exothermic and the heat evolved is sufficient to boil the water and sulfuric acid mixture.
- The reaction mixture is then cooled and the acetic acid is purified by distillation.

Conclusion

Hence, option A, i.e., acetic acid is the correct answer.
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Ethyl alcohol on oxidation with K₂Cr₂O₇ givesa) ...
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Ethyl alcohol on oxidation with K₂Cr₂O₇ givesa) Acetic acid b) Acetaldehyde c) Formaldehyde d) Formic acid Correct answer is option 'A'. Can you explain this answer?
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