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Select the correct statements about solid crystals:
  • a)
    High pressure decreases co-ordination number
  • b)
    High pressure increases co-ordination number
  • c)
    High temperature increases co-ordination number
  • d)
    High temperature decreases co-ordination number
Correct answer is option 'B,D'. Can you explain this answer?
Most Upvoted Answer
Select the correct statements about solid crystals:a)High pressure dec...
Pressure is directly proportional to coordination number. with the increase in pressure, the constituent particles move closer hence the coordination number increases.
High temperature decreases co-ordination number.
For example:
If we heat the CsCl structure at high temperature it gets converted to NaCl structure. Thus, there is an decrease in the co-ordination number on increasing the temperature.
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Community Answer
Select the correct statements about solid crystals:a)High pressure dec...
Understanding Coordination Number in Solid Crystals
The coordination number in solid crystals refers to the number of nearest neighbor atoms or ions surrounding a given atom or ion. This property is influenced by both temperature and pressure.
Effect of High Pressure
- High pressure tends to increase the coordination number.
- As pressure is applied, atoms are forced closer together.
- This proximity allows for more neighboring atoms to influence a central atom, resulting in a larger coordination number.
Effect of High Temperature
- At high temperatures, the coordination number can decrease.
- Increased thermal energy leads to greater atomic vibrations and movement.
- The atoms may become too agitated to maintain close proximity with as many neighbors, thus reducing the coordination number.
Summary of Effects
- High Pressure: Increases coordination number (Option B).
- High Temperature: Decreases coordination number (Option D).
Understanding these effects is crucial for predicting the behavior and properties of materials under varying conditions, including their stability and reactivity.
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Select the correct statements about solid crystals:a)High pressure decreases co-ordination numberb)High pressure increases co-ordination numberc)High temperature increases co-ordination numberd)High temperature decreases co-ordination numberCorrect answer is option 'B,D'. Can you explain this answer?
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