Chemistry Exam  >  Chemistry Questions  >  The correct statement about the Cu–N bo... Start Learning for Free
The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:
  • a)
    All the bond distance are equal.
  • b)
    The axial bonds are longer than the equatorial ones.
  • c)
    The equatorial bonds are longer than the axial ones.
  • d)
    All the bond distances are unequal.
Correct answer is option 'B'. Can you explain this answer?
Most Upvoted Answer
The correct statement about the Cu–N bond distance in [Cu(NH3)6]...
Explanation:

- [Cu(NH3)6]2+ is an octahedral complex with Cu2+ ion at the center and six NH3 ligands arranged in an octahedral geometry around it.
- The octahedral geometry has two types of bonds, axial bonds, and equatorial bonds.

Axial bonds:

- The axial bonds are formed between the Cu2+ ion and the two NH3 ligands located along the z-axis.
- These bonds are oriented along the axis of symmetry of the octahedron.
- Due to the presence of the axial ligands, the Cu2+ ion is pushed away from the center of the octahedron, resulting in longer bond distances.

Equatorial bonds:

- The equatorial bonds are formed between the Cu2+ ion and the four NH3 ligands located in the xy-plane.
- These bonds are oriented in the plane of the octahedron.
- The presence of the equatorial ligands does not push the Cu2+ ion away from the center of the octahedron, resulting in shorter bond distances.

Conclusion:

- Therefore, the axial bonds in [Cu(NH3)6]2+ are longer than the equatorial bonds, making option B the correct answer.
Free Test
Community Answer
The correct statement about the Cu–N bond distance in [Cu(NH3)6]...
Explanation:

- In [Cu(NH3)6]2+, there are six NH3 ligands arranged in an octahedral geometry around the central Cu2+ ion.
- The bond distances are different due to the difference in the orientation of the ligands.
- There are two types of bond distances in this complex: axial and equatorial.
- Axial bonds: These are the bonds that are perpendicular to the plane of the equatorial bonds. There are two axial bonds in this complex.
- Equatorial bonds: These are the bonds that lie in the plane of the complex. There are four equatorial bonds in this complex.
- The repulsion between the lone pairs of electrons on the NH3 ligands causes the axial bonds to be longer than the equatorial bonds.
- Therefore, the correct statement is that the axial bonds are longer than the equatorial ones (option B is correct).
Explore Courses for Chemistry exam
The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer?
Question Description
The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer?.
Solutions for The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer? in English & in Hindi are available as part of our courses for Chemistry. Download more important topics, notes, lectures and mock test series for Chemistry Exam by signing up for free.
Here you can find the meaning of The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer?, a detailed solution for The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer? has been provided alongside types of The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice The correct statement about the Cu–N bond distance in [Cu(NH3)6]2+ is:a)All the bond distance are equal.b)The axial bonds are longer than the equatorial ones.c)The equatorial bonds are longer than the axial ones.d)All the bond distances are unequal.Correct answer is option 'B'. Can you explain this answer? tests, examples and also practice Chemistry tests.
Explore Courses for Chemistry exam
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev