Which of the following compound do/es not show/s mutarotation?a)Glucos...
Muta rotation is the process involving gradual change in optical rotation of either form of carbohydrate in aqueous solution to that of equilibrium mixture the structure of sucrose shows that it does not have free CHO and CO groups.
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Which of the following compound do/es not show/s mutarotation?a)Glucos...
Mutarotation:
Mutarotation is the spontaneous change in the specific rotation of an optically active compound when it is dissolved in a solvent or when it is heated. It occurs due to the interconversion between different anomers of a compound.
a) Glucose:
Glucose is a sugar molecule that exists in a cyclic form in solution. It can exist in two different forms known as anomers: α-glucose and β-glucose. These anomers interconvert in solution, resulting in mutarotation. The specific rotation of glucose changes over time when dissolved in a solvent.
b) Fructose:
Fructose is another sugar molecule that exists in a cyclic form in solution. Similar to glucose, it can exist in two different forms: α-fructose and β-fructose. These anomers can also interconvert in solution, leading to mutarotation.
c) Maltose:
Maltose is a disaccharide composed of two glucose molecules. Each glucose molecule in maltose can exist in its cyclic form and exhibit mutarotation. Therefore, maltose undergoes mutarotation.
d) Sucrose:
Sucrose is a disaccharide composed of glucose and fructose molecules. Unlike glucose and fructose, sucrose does not have a free anomeric carbon, which is necessary for mutarotation. Thus, sucrose does not undergo mutarotation.
Conclusion:
The compound that does not show mutarotation is sucrose (option D). Sucrose lacks a free anomeric carbon and therefore cannot interconvert between different anomers, resulting in a constant specific rotation over time in a solvent.