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How many different alkyne isomers upon hydrogenation in the presence of CaCO3 / Pd gives 4-methyl hexene which is simultaneously c/s at double bond?
    Correct answer is '2'. Can you explain this answer?
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    How many different alkyne isomers upon hydrogenation in the presence o...
    Solution:

    Given: Hydrogenation of alkyne in the presence of CaCO3 / Pd gives 4-methyl hexene which is simultaneously cis/trans at double bond.

    To find: Number of different alkyne isomers.

    Step 1: Write the formula of 4-methyl hexene.

    4-methyl hexene formula: CH3-CH2-CH=CH-CH2-CH3

    Step 2: Draw the structural formula of 4-methyl hexene.

    H H
    │ │
    H-C-C-C=C-C-H
    │ │
    H CH3

    Step 3: Identify the position of the double bond.

    Double bond is present between 3rd and 4th carbon atoms.

    Step 4: Identify the alkynes which can give 4-methyl hexene upon hydrogenation in the presence of CaCO3 / Pd.

    There are 2 possible alkyne isomers which can give 4-methyl hexene upon hydrogenation in the presence of CaCO3 / Pd.

    - 3-methyl-1-pentene - This alkyne can give 4-methyl hexene upon hydrogenation in the presence of CaCO3 / Pd. The double bond is present between 2nd and 3rd carbon atoms. On hydrogenation, the double bond is converted into a single bond and a methyl group is added to the 3rd carbon atom.
    - 2-methyl-2-pentene - This alkyne can also give 4-methyl hexene upon hydrogenation in the presence of CaCO3 / Pd. The double bond is present between 2nd and 3rd carbon atoms. On hydrogenation, the double bond is converted into a single bond and a methyl group is added to the 4th carbon atom.

    Both of these alkyne isomers give 4-methyl hexene which is simultaneously cis/trans at double bond.

    Therefore, the correct answer is '2'.
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    Community Answer
    How many different alkyne isomers upon hydrogenation in the presence o...
    Yes cis when both side left and right side double bond same thing same side
    So ch3-c ///c-cch2ch3
    where this /// denotes triple bond
    here h h on same side on hydrogenation
    ch3ch2ch2cch3///chch3
    where /// is triple bond here ch 3 ch 3 on same side
    it is not EZ configuration but cis trans Bhai
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