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A complex cation is formed by Pt (in same oxidation state) with ligands (in proper number so that coordination number of Pt becomes six). Which of the following can be its correct IUPAC name ?
  • a)
    Diammineethylenediaminedithiocyanato-Splatinum(II) ion
  • b)
    Diamminedithiocyanato-Sethylenediamineplatinum(IV) ion
  • c)
    Diammineethylenediaminedithiocyanato-Splatinum(IV) ion
  • d)
    Diamminebis(ethylenediamine)dithiocyanate-
    S-platinum(IV) ion
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
A complex cation is formed by Pt (in same oxidation state) with ligand...
Option c is correct.
in diammineethylenediaminedithiocyanato-S platinum (IV) ion
ammine is a monodentate ligand ,it is di- so 2 ammine are present.
ethylene diamine is a bidentate ligand , it is single so 2 eectrons are coordinated by it.
thiocyanato is a monodentate ligand and it is di- so it coordinates 2 electrons.
Therefore, adding them all 6 electrons are contributed and the coordination number of platinum becomes 6.
So., option c is correct as in other options the coordination number is not 6.
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Community Answer
A complex cation is formed by Pt (in same oxidation state) with ligand...
Explanation:

Given Complex Cation:
- Pt ion with ligands forming a complex with a coordination number of six.

Correct IUPAC name:
- Diammineethylenediaminedithiocyanato-Splatinum(IV) ion

Reasoning:
- The complex has Pt in the +4 oxidation state, hence the Roman numeral IV in the name.
- The ligands are diammine, ethylenediamine, and dithiocyanato, forming a coordination number of six around Pt.
- The ligands are named in alphabetical order, so ethylenediamine comes before dithiocyanato in the name.
- The order of ligands in the name is based on their alphabetical order rather than their position around the central atom.

Incorrect Options:
a) Diammineethylenediaminedithiocyanato-Splatinum(II) ion - Incorrect oxidation state for Pt
b) Diamminedithiocyanato-Sethylenediamineplatinum(IV) ion - Incorrect ligand order
d) Diamminebis(ethylenediamine)dithiocyanate-S-platinum(IV) ion - Incorrect ligand order and naming
Therefore, the correct IUPAC name for the complex cation with Pt in the same oxidation state and a coordination number of six is Diammineethylenediaminedithiocyanato-Splatinum(IV) ion.
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A complex cation is formed by Pt (in same oxidation state) with ligands (in proper number so that coordination number of Pt becomes six). Which of the following can be its correct IUPAC name ?a)Diammineethylenediaminedithiocyanato-Splatinum(II) ionb)Diamminedithiocyanato-Sethylenediamineplatinum(IV) ionc)Diammineethylenediaminedithiocyanato-Splatinum(IV) iond)Diamminebis(ethylenediamine)dithiocyanate-S-platinum(IV) ionCorrect answer is option 'C'. Can you explain this answer?
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A complex cation is formed by Pt (in same oxidation state) with ligands (in proper number so that coordination number of Pt becomes six). Which of the following can be its correct IUPAC name ?a)Diammineethylenediaminedithiocyanato-Splatinum(II) ionb)Diamminedithiocyanato-Sethylenediamineplatinum(IV) ionc)Diammineethylenediaminedithiocyanato-Splatinum(IV) iond)Diamminebis(ethylenediamine)dithiocyanate-S-platinum(IV) ionCorrect answer is option 'C'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about A complex cation is formed by Pt (in same oxidation state) with ligands (in proper number so that coordination number of Pt becomes six). Which of the following can be its correct IUPAC name ?a)Diammineethylenediaminedithiocyanato-Splatinum(II) ionb)Diamminedithiocyanato-Sethylenediamineplatinum(IV) ionc)Diammineethylenediaminedithiocyanato-Splatinum(IV) iond)Diamminebis(ethylenediamine)dithiocyanate-S-platinum(IV) ionCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for A complex cation is formed by Pt (in same oxidation state) with ligands (in proper number so that coordination number of Pt becomes six). Which of the following can be its correct IUPAC name ?a)Diammineethylenediaminedithiocyanato-Splatinum(II) ionb)Diamminedithiocyanato-Sethylenediamineplatinum(IV) ionc)Diammineethylenediaminedithiocyanato-Splatinum(IV) iond)Diamminebis(ethylenediamine)dithiocyanate-S-platinum(IV) ionCorrect answer is option 'C'. Can you explain this answer?.
Solutions for A complex cation is formed by Pt (in same oxidation state) with ligands (in proper number so that coordination number of Pt becomes six). Which of the following can be its correct IUPAC name ?a)Diammineethylenediaminedithiocyanato-Splatinum(II) ionb)Diamminedithiocyanato-Sethylenediamineplatinum(IV) ionc)Diammineethylenediaminedithiocyanato-Splatinum(IV) iond)Diamminebis(ethylenediamine)dithiocyanate-S-platinum(IV) ionCorrect answer is option 'C'. Can you explain this answer? in English & in Hindi are available as part of our courses for Class 12. Download more important topics, notes, lectures and mock test series for Class 12 Exam by signing up for free.
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