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Aniline does not undergo Friedel – Crafts reaction
  • a)
    Anilium ion deactivates any further reaction.
  • b)
    aluminium chloride, the catalyst reacts with NH2 group
  • c)
    nitrogen of aniline acquires positive charge
  • d)
    all of these
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
Aniline does not undergo Friedel – Crafts reactiona)Anilium ion ...
NH2 has lp of electron which reacts with AlCl3 or other catalyst that we add to form anilium ion.
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Read the passage given below and answer the following questions:Reductive alkylation is the term applied to the process of introducing alkyl groups into ammonia or a primary or secondary amine by means of an aldehyde or ketone in the presence of a reducing agent. The present discussion is limited to those reductive alkylations in which the reducing agent is hydrogen and a catalyst or "nascent" hydrogen, usually from a metalacid combination; most of these reductive alkylations have been carried out with hydrogen and a catalyst. The principal variation excluded is that in which the reducing agent is formic acid or one of its derivatives; this modification is known as the Leuckart reaction. The process of reductive alkylation of ammonia consists in the addition of ammonia to a carbonyl compound and reduction of the addition compound or its dehydration product. The reaction usually is carried out in ethanol solution when the reduction is to be effected catalytically:Since the primary amine is formed in the presence of the aldehyde it may react in the same way as ammonia, yielding an additional compound, a Schiff's base (RCH= NCH2R) and finally, a secondary amine. Similarly, the primary amine may react with the imine, forming an addition product which also is reduced to a secondary amine Finally, the secondary amine may react with either the aldehyde or the imine to give products which are reduced to tertiary amines.Similar reactions may occur when the carbonyl compound employed is a ketone.Q. The reaction of ammonia and its derivatives with aldehydes is called

Aniline does not undergo Friedel – Crafts reactiona)Anilium ion deactivates any further reaction.b)aluminium chloride, the catalyst reacts with NH2 groupc)nitrogen of aniline acquires positive charged)all of theseCorrect answer is option 'D'. Can you explain this answer?
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Aniline does not undergo Friedel – Crafts reactiona)Anilium ion deactivates any further reaction.b)aluminium chloride, the catalyst reacts with NH2 groupc)nitrogen of aniline acquires positive charged)all of theseCorrect answer is option 'D'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Aniline does not undergo Friedel – Crafts reactiona)Anilium ion deactivates any further reaction.b)aluminium chloride, the catalyst reacts with NH2 groupc)nitrogen of aniline acquires positive charged)all of theseCorrect answer is option 'D'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Aniline does not undergo Friedel – Crafts reactiona)Anilium ion deactivates any further reaction.b)aluminium chloride, the catalyst reacts with NH2 groupc)nitrogen of aniline acquires positive charged)all of theseCorrect answer is option 'D'. Can you explain this answer?.
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