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Law of Equipartition of energy (Degrees of Freedom) Video Lecture - NEET

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1. What is the Law of Equipartition of energy?
Ans. The Law of Equipartition of energy states that in thermal equilibrium, the total energy of a system is equally distributed among all of its degrees of freedom. This means that each degree of freedom, such as translational, rotational, and vibrational motion, contributes an equal amount of energy to the system.
2. How does the Law of Equipartition of energy relate to the concept of degrees of freedom?
Ans. The Law of Equipartition of energy is directly related to the concept of degrees of freedom. Degrees of freedom refer to the independent ways in which a system can store and distribute energy. According to the law, each degree of freedom contributes an equal amount of energy to the system when it is in thermal equilibrium.
3. What are the implications of the Law of Equipartition of energy in different states of matter?
Ans. The Law of Equipartition of energy has different implications depending on the state of matter. In solids, the law predicts that each atom or molecule has three degrees of freedom for translational motion and three degrees of freedom for vibrational motion. In liquids and gases, additional degrees of freedom for rotational motion are considered. These predictions help in understanding the specific heat capacities and other thermodynamic properties of different states of matter.
4. How does the Law of Equipartition of energy explain the behavior of gases?
Ans. The Law of Equipartition of energy explains the behavior of gases by considering the various degrees of freedom associated with gas molecules. For example, in an ideal gas, each molecule has three degrees of freedom for translational motion and two additional degrees of freedom for rotational motion. This law helps in understanding the relationship between temperature, kinetic energy, and the behavior of gas molecules.
5. What are the limitations of the Law of Equipartition of energy?
Ans. The Law of Equipartition of energy has certain limitations. It assumes that all degrees of freedom of a system are equally excited and contribute equally to the total energy. However, in some cases, certain degrees of freedom may not be excited or may contribute a different amount of energy. Additionally, the law does not consider quantum effects, which become significant at low temperatures. Therefore, the law is not applicable for systems at very low temperatures or for systems involving quantum mechanical effects.
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