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Matrix-Match & Integer Answer Type Questions: The Solid State & Surface Chemistry | JEE Advanced | 35 Years Chapter wise Previous Year Solved Papers for JEE PDF Download

Direction : question contains statements given in two columns, which have to be matched. The statements in Column-I are labelled A, B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in
 Column-II

Qn.

Match the crystal system/unit cells mentioned in Column I with their characteristic features mentioned in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 × 4 matrix given in the ORS.

Column I
Column II
(A) Simple cubic and face-centered cubic parameters
(p) have these parameters, a = b = c and α = β = γ
(B) cubic and rhombohedral
(q) are two crystal systems
(C) cubic and tetragonal
(r) have only two crystallo-graphic angles of 90°
(D) hexagonal and monoclinic
(s) belong to same crystal system

Ans:

(A - p, s); (B - p, q); (C - q); (D - q, r).

 

Solution:

A→ p, s; Parameters of a cubic system are a = b = c and α = β = γ= 90°
 There are three types of lattices in cubic system
 These are simple, Face centred and body centred B→ p, q ; The parameters of a Rhombohedral system are a = b = c; α = β = γ = 90°
 Cubic and Rhombohedral are two crystal systems. There are seven crystal systems in all C→ q; These are two crystal systems.
 D→ q, r; Hexagonal and monoclinic are two crystal systems.
 The parameters of these are
 Hexagonal; a = b ≠ c and α = β = 90°, r = 120°
 Monoclinic ; a ≠ b ≠ c and α = γ = 90°,β ≠ 90°


Integer Value Correct Type Question

Q. The number of hexagonal faces that are present in a truncated octahedron is (2011)


Ans: b

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FAQs on Matrix-Match & Integer Answer Type Questions: The Solid State & Surface Chemistry - JEE Advanced - 35 Years Chapter wise Previous Year Solved Papers for JEE

1. What is the importance of solid state chemistry in JEE Advanced?
Ans. Solid state chemistry is an important topic in JEE Advanced as it covers concepts related to the structure, properties, and behavior of solids. Questions related to crystal structures, unit cells, crystal defects, and their effects on properties are frequently asked in the exam. Understanding solid state chemistry is crucial for solving complex problems in materials science and engineering.
2. How can I understand the concept of crystal structures in solid state chemistry?
Ans. Understanding crystal structures in solid state chemistry can be achieved through visualizing the arrangement of atoms or ions in a crystal lattice. One approach is to use models or diagrams to represent the unit cell and its symmetry elements. Another approach is to study the mathematical description of crystal structures using concepts like Bravais lattices, crystal systems, and Miller indices. Practice with examples and visual aids can greatly aid in comprehending crystal structures.
3. What are crystal defects and how do they affect the properties of solids?
Ans. Crystal defects are irregularities or deviations from the ideal arrangement of atoms or ions in a crystal lattice. These defects can be classified into point defects, line defects, and plane defects. Point defects, such as vacancies and interstitials, can affect the mechanical, electrical, and optical properties of solids. Line defects, like dislocations, can influence the plasticity and strength of materials. Plane defects, such as grain boundaries, can impact the conductivity and corrosion resistance of solids.
4. How does surface chemistry relate to solid state chemistry?
Ans. Surface chemistry is closely related to solid state chemistry as it deals with the study of chemical reactions and phenomena occurring at the interfaces between solid materials and gases or liquids. It involves concepts like adsorption, catalysis, and surface tension, which are relevant in understanding the behavior of solid surfaces. Surface chemistry plays a significant role in areas such as heterogeneous catalysis, corrosion, and nanotechnology.
5. What are the applications of solid state and surface chemistry in real-world scenarios?
Ans. Solid state and surface chemistry have diverse applications in various fields. In materials science, they are utilized in the development of new materials with tailored properties, such as high-performance ceramics, semiconductors, and superconductors. In environmental science, these branches help in understanding and mitigating pollution through adsorption and catalytic processes. In the pharmaceutical industry, they contribute to drug delivery systems and formulation development. Additionally, solid state and surface chemistry play a crucial role in energy storage, electronic devices, and sensors.
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